Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 4, Pages 571-575Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.11.058
Keywords
Intermolecular hydroarylation; Gold(I)-catalysis; Allene; Indole
Categories
Funding
- NSF [CHE-0555425]
- NIH [GM-080422]
- JohnsonJohnson
- Pharmacological Sciences Training Program fellowship
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Reaction of a monosubstituted, 1,3-disubstituted, or tetrasubstituted allene with various indoles catalyzed by a 1:1 mixture of a gold(I) N-heterocyclic carbene complex and AgOTf at room temperature leadsto hydroarylation with formation of 3-allyl-indoles in modest to good yield. (C) 2008 Elsevier B.V. All rights reserved.
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