Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 2, Pages 143-149Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.10.032
Keywords
Cobalt; Cycloadditions; Cyclotrimerizations; Computational methods; Ruthenium
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Funding
- MICINN [CTQ2005-08613, CTQ2008-06557]
- Consolider Ingenio 2010 [CSD2007-00006]
- Xunta de Galicia [2007/XA084, INCITE08PXIB209024PR]
- Ramon y Cajal research
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Computational methods have been used to better understand both the CpRuCl- and CpCo-catalyzed and mediated cyclotrimerization of alkynes and the [2+2+2] cycloaddition of alkynes to alkenes. These studies have allowed more accurate mechanisms to be proposed for each of these transformations and for some previously proposed intermediates to be discarded. The mechanistic rationale of these processes depends on the nature of the metal, ligands and substrate partners. (C) 2008 Elsevier B. V. All rights reserved.
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