Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 6, Pages 2723-2728Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402829b
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An efficient asymmetric synthesis of atorvastatin calcium has been achieved from commercially available diethyl 3-hydroxyglutarate through a novel approach that involves an organocatalytic enantioselective cyclic anhydride desymmetrization to establish C(3) stereogenicity and cyanide-free assembly of C-7 amino type side chain via C-5+C-2 strategy as the key transformations.
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