Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 17, Pages 8010-8019Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo5011334
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- CSIR, New Delhi
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The palladium-catalyzed intramolecular oxidative coupling described herein involves a double C(sp(2))-H bond functionalization in sulfonanilides, providing a workable access to biaryl sultams annulated into a six-membered ring that are otherwise difficult to obtain by literature methods. The other synthetic applications of this protocol including the synthesis of biaryl sultams containing a seven-membered ring and analogous sultones are also presented.
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