Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 16, Pages 8191-8197Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo401259w
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Funding
- INSA Rouen
- Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- Region Haute-Normandie
- Immunochim project [34209]
- European Union
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Highly atroposelective Meyers' lactamization promoted by pivalic acid under microwave irradiation is reported which allows the construction of nonracemic substituted-dibenzo(di)azepine derivatives through a center to axial chirality transfer principle, controlling the otherwise configurationally labile biaryl axis. This approach provides a straightforward entry to enantioenriched analogues of biorelevant architectures.
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