Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 23, Pages 11756-11764Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo401722e
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- UGC New Delhi
- CSIR, New Delhi [CSC0108]
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A general organocatalytic strategy for asymmetric synthesis of both syn/anti-1,3-diamines has been developed. The strategy employs proline-catalyzed sequential alpha-amination and Horner-Wadsworth-Emmons (HWE) olefination of aldehydes as the key step where syn-1,3-diamine was obtained as the most favorable product.
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