Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 24, Pages 11355-11361Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo302068e
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- CSIR, New Delhi
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A domino cycloisomerization/Pictet-Spengler reaction of 2-(4-aminobut-1-yn-1-yl)aniline with aldehydes has been achieved using a AuIPrCl (5 mol %)/AgSbF6 (10 mol %) catalytic system to produce the corresponding 1-aryl-N-tosyl-2,3,4,5-tetrahydropyrido[4,3-b] indole derivatives in good yields. This is the first report on the synthesis of tetrahydro pyrido[4,3-b]indole scaffolds through as tandem 5-endo-dig cyclization and Pictect-Spengler reaction.
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