Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 18, Pages 8329-8331Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300831u
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Funding
- Center for Advanced Soft Electronics under Global Frontier Research Program [2011-0031636]
- Converging Research Center Program of the Ministry of Education, Science and Technology, Republic of Korea [2011K00611]
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We developed a new synthetic method for bicyclo[2.2.2]-octadiene (BCOD)-fused porphyrin (1), a tetrabenzoporphyrin (TBP, 2) precursor that is well-known as a good material for use in organic electronic devices. The newly developed method synthesizes the BCOD-fused pyrrole intermediate (which is the most important intermediate in synthesizing BCOD-fused porphyrin) in a simpler and easier manner than other existing methods, and thus, the new method can efficiently synthesize the TBP precursor.
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