Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 8, Pages 4046-4062Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo3004106
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Funding
- FAEP-UNICAMP
- FAPESP
- CNPq
- INCT-INOFAR (Proc. CNPq) [573.564/2008-6]
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A stereoselective total synthesis of the reported structure of goniotrionin (4) has been accomplished. The key steps involved the opening of a chiral epoxide, a highly diastereoselective Mukaiyama aerobic oxidative cyclization, a selective 1,2-syn Mukaiyama aldol reaction, and a Noyori reduction.
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