Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 14, Pages 5884-5893Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300779q
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Funding
- ACS Petroleum Research Fund [47565-G1]
- Research Corporation for Science Advancement
- University of Minnesota
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Prior examples of hydroacylation to form six- and seven-membered ring ketones require either embedded chelating groups or other substrate design strategies to circumvent competitive aldehyde decarbonylation. A cooperative catalysis strategy enabled intramolecular hydroacylation of disubstituted alkenes to form seven- and six-membered rings without requiring substrate-embedded chelating groups.
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