Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 11, Pages 4715-4720Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo200320k
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- Natural Sciences and Engineering Research Council of Canada (NSERC)
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Ionic diamine rhodium complex (1) catalyzes the reductive N-cyclization of 2-vinylnitroarenes using carbon monoxide as a reducing agent to afford functionalized indoles. The catalytic system allows direct access to indoles with ester and ketone groups at the 2- or 3-position, in good yields.
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