Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 23, Pages 9841-9844Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2015664
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Chemoselective reduction of nitro groups in the presence of activated heteroaryl halides was achieved via catalytic hydrogenation with a commercially available sulfided platinum catalyst. The optimized conditions employ low temperature, pressure, and catalyst loading (<0.1 mol % Pt) to afford heteroaromatic amines with minimal hydrodehalogenation byproducts.
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