Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 16, Pages 6611-6618Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2009164
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- KRICT
- Ministry of Knowledge Economy, Korea
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Highly stereoselective, palladium-catalyzed alpha-arylation reactions of 3-aryl-1-indanones with aryl bromides are described. The use of sodium tert-butoxide as a base in this process is required to elevate the efficiencies and stereoselectivities of these reactions. The new methodology was successfully applied to a highly efficient route for the asymmetric synthesis of (+)-pauciflorol F.
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