Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 14, Pages 5524-5530Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo200573y
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- National Council of Taiwan [97-2628-M-001-015-MY3]
- Academia Sinica
- Fu-Jen Catholic University
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A bis-phenylethynyl thiophene derivative functionalized with long-chain pyridyl biscarboxamides displayed unique helical morphology in the xerogel form via nicely complementary intermolecular interactions. The helical nanostructures visualized by TEM and AFM remarkably matched well with the computational results. Supramolecular chirality can be amplified by coassembly of a chiral conductor to bias the helical arrangement.
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