4.7 Article

Synthesis and Application of a Chiral Diborate

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 7, Pages 2324-2327

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo102559s

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Funding

  1. Alfried Krupp von Bohlen und Halbach Foundation

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A chiral diborate with different counterions is reported whose structure was unambiguously confirmed by X-ray analysis. This chiral dianion was used in the resolution of trans-1,2-diamines and also as a chiral shift reagent for NMR analysis of triphenylphosphonium salts.

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