Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 18, Pages 7623-7628Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201578z
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Funding
- Shorai Foundation for Science and Technology
- RIKEN
- Grants-in-Aid for Scientific Research [22750209] Funding Source: KAKEN
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The absolute configuration of a binaphthylazobenzene dyad 2b, which has a chiral axis and a chiral plane, was determined by comparing the experimental circular dichroism (CD) spectra with the theoretical CD spectra calculated by the time-dependent (TD)-DFT method. The CD signals of the trans-azobenzene moiety indicated that the two benzene rings of this moiety are twisted unidirectionally. It is suggested that these dyads with shorter linkers may be suitable for use as chiroptical switches.
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