Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 8, Pages 2635-2647Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo1025767
Keywords
-
Categories
Funding
- European Social Fund [2009/0203/1DP/1.1.1.2.0/09/APIA/VIAA/023]
Ask authors/readers for more resources
Chiral, nonracemic o-aminobenzylamines were prepared in a highly diastereoselective reduction of atropisomeric N-tert-butanesulfinylketimines. The ortho-substituent ensures the distinct reactivity of atropisomers 4d-f. The free energy of activation for atropisomerization of sulfinylimines 4d-f in THF-d(8) was determined by NMR methods to range from 70.8 to 97.9 kJ/mol.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available