4.7 Article

Rhodium(I)-Catalyzed Cycloisomerization of 1,6-Enynes to Bicyclo[4.1.0]heptenes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 4, Pages 1281-1284

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo902273x

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Funding

  1. Brain Korea 21
  2. Seoul Science Fellowships
  3. National Research Foundation of Korea [2008-0057557] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Efficient rhodium(I)-catalyzed cyclopropanation reactions of nitrogen-tethered 1,6-enynes to azabicyclo[4.1.0]heptenes are reported. Moreover, rhodium(l)-catalyzed tandem cycloisomerization and carbonylative [3+3+1] cycloaddition reactions of a cyclopropylenyne have been observed.

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