Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 10, Pages 3484-3487Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo1003828
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Funding
- Hunan Provincial Education Department [08B053, 08A037]
- Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China) [KLCBTCMR2008-11]
- New Century Excellent Talents in University [NCET-06-0711]
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A selective protocol for the synthesis of 2-methylene-3-substituted-2,3-dihydro-1H-inden-1-ones and 2-benzylidene-2,3-dihydro-1H-inden-1-ones has been developed via palladium-catalyzed cyclocarbonylation reactions of arynes with allyl carbonates and carbon monooxide (CO). It is noteworthy that the selectivity of this new route is depended on both substrates and ligands.
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