Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 24, Pages 9573-9575Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902235h
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Funding
- UCM-BSCH [GR58/08-910815, CTQ2006-15279-C03-01, SAF2006-04698]
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The NHC-catalyzed conjugate hydroacylation of 1,4-naphthoquinones allows for the synthesis of monoacylated 1,4-dihydroxynaphthalene derivatives. These targets, difficult to prepare selectively by standard protocols, represent important intermediates in the elaboration of highly substituted 1,4-naphthoquinone derivatives, which constitute relevant pharmaceutical scaffolds. High regioselectivity has been observed in the hydroacylation reaction when starting from nonsymmetrical quinones.
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