Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 15, Pages 5691-5694Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo900847u
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Funding
- New Century Excellent Talents in University [NCET-06-0711]
- Hunan Provincial Education Department [08B053, 08A037]
- KLCBTCMR [KLCBTCMR2008-11]
- Hunan Normal University [080605]
- National Natural Science Foundation of China [20872112]
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A mild method for selective synthesis of o-acylbenzylphosphonates has been developed by the reactions of arynes with beta-ketophosphonates. In the presence of CsF and THF, the carbon-carbon sigma-bonds of 2-oxopropylphosphonates were selectively cleaved and added to arynes providing the corresponding 2-acylbenzylphosphonates in moderate to good yields.
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