Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 2, Pages 888-890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801725j
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Funding
- Natural Sciences and Engineering Research Council of Canada
- National Natural Science Foundation of China [20672040, 20872043]
- program for new century excellent talents in university [NCET-05-0672]
- National Basic Research Program of China [2004CCA00100]
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Palladium-catalyzed ring-opening thiocarbonylation of vinylcyclopropanes (VCPs) with thiols and carbon monoxide affords the corresponding unsaturated thioesters in moderate to excellent yields. This reaction provides a general method for the ring-opening thiocarbonylation of VCPs. It further demonstrates the utility of transition metal catalysts for the synthesis of organosulfur compounds.
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