Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 21, Pages 8502-8510Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo801577t
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Amino acid esters 5-11 as tyrosine mimics have been synthesized in excellent enantioselectivity (up to 99.6% ee) and in good overall chemical yields. The key step in the sequence was the Burk's [Rh(COD)(2R,5R)-Et-DuPhos]BF(4)-catalyzed asymmetric hydrogenation of enamides with a variety of reactive functional groups.
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