Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 6, Pages 2416-2419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo702680p
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[GRAPHICS] Novel C6-phosphonated purine nucleosides were obtained in good to excellent isolated yields by the simple and catalyst-free SNAr-Arbuzov reaction of trialkyl phosphite with 6-choloropurine nucleosides, including a series of nonsugar carbon nucleosides. Shorter reaction times were needed, and substantially higher yields were obtained under microwave irradiation conditions compared with conventional heating conditions.
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