Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 73, Issue 18, Pages 6994-7002Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8010649
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Funding
- NRSC-Catalysis, the European Community's 6th Framework Programme
- Pharmaceutical Analysis
- Department of Pharmacy
- University of Groningen
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With a consecutive asymmetric allylic alkylation (AAA)/cross-metathesis (CM)/conjugate addition (CA) protocol it is possible to synthesize either stereoisomer of compounds containing a vicinal dialkyl array with excellent stereoselectivity. The versatility of this protocol in natural product synthesis is demonstrated in the preparation of the ant pheromones faranal and lasiol.
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