Journal
PHYSICAL REVIEW A
Volume 92, Issue 3, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.92.032508
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Funding
- SPbU Fundamental Science Research [0.38.652.2013]
- Russian Foundation for Basic Research [13-02-01406]
- President of the Russian Federation [MK-5877.2014.2]
- Deutsche Forschungsgemeinschaft
- Land Niedersachsen
- Pomona College Sontag Fellowship Program
- U.S. Department of Energy, Office of Science [DE-SC0012704]
- Division of Chemical Sciences, Geosciences and Biosciences within the Office of Basic Energy Sciences
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We report the results of our theoretical study and analysis of earlier experimental data for the g-factor tensor components of the ground (2)Pi(1/2) state of the free PbF radical. The values were obtained both within the relativistic coupled-cluster method combined with the generalized relativistic effective core potential approach and with our fit of the experimental data from [R. J. Mawhorter, B. S. Murphy, A. L. Baum, T. J. Sears, T. Yang, P. M. Rupasinghe, C. P. McRaven, N. E. Shafer-Ray, L. D. Alphei, and J.-U. Grabow, Phys. Rev. A 84, 022508 (2011); A. L. Baum, B. A. thesis, Pomona College, 2011]. The obtained results agree very well with each other but contradict the previous fit performed in the cited works. Our final prediction for g factors is G(parallel to) = 0.081(5), G(perpendicular to) = -0.27(1).
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