Article
Chemistry, Analytical
Bing Liu, Hanyu Tang, Qian Liu, Wenwen Wang, Haitao Li, Shiya Zheng, Fei Sun, Xiangwei Zhao
Summary: In this study, a novel surface-enhanced Raman scattering-based Western blot (SERS-WB) was proposed for accurate quantitative detection of low-abundance proteins. SERS nanotags were used as quantitative labels of proteins, and the target protein on the membrane could be directly identified by colorimetric signal due to the aggregation effect of nanoparticles.
Article
Chemistry, Applied
Alisa I. Shevchuk, Vasilisa O. Svinko, Aleksei N. Smirnov, Elena V. Solovyeva
Summary: The combined use of dyes and plasmonic nanoparticles provides new opportunities for the development of SERS tags. This study reports the detailed SERS study of cyanine5.5 and cyanine7.5 derivatives interaction with gold nanoparticles. The results provide useful findings for obtaining SERS and bimodal Raman-fluorescence nanotags containing dyes.
Article
Engineering, Biomedical
Pengfei Sun, Xinyue Jiang, Bo Sun, Hong Wang, Jiewei Li, Quli Fan, Wei Huang
Summary: Designing conjugated polymers with efficient NIR-II fluorescence and photothermal therapy performance is challenging. This study addresses the issue by adjusting the electron acceptor density, leading to enhanced fluorescence and photothermal effects. Nanoparticles based on these polymers exhibit high brightness fluorescence and photothermal conversion efficiency.
Review
Chemistry, Multidisciplinary
Wenqi Wang, Xiaowen He, Mingzhi Du, Chen Xie, Wen Zhou, Wei Huang, Quli Fan
Summary: NIR-II fluorescence imaging using 1,064 nm excitation shows higher tissue penetration depth and resolution compared to NIR-I wavelength excited dyes, leading to broader imaging applications. This review summarizes recent advances in 1,064 nm excited NIR-II fluorescence fluorophores for bioimaging, focusing on small molecule dyes and semiconducting polymers. The improved performance of these dyes has implications for future developments in bioimaging techniques.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Takao Fukuoka, Toshiya Yasunaga, Kyoko Namura, Motofumi Suzuki, Akinobu Yamaguchi
Summary: Plasmonic nanomaterials have shown potential in combating counterfeit drugs by providing a method for on-dose authentication of tablets. Nanotags consisting of self-assemblies of colloidal gold nanoparticles can produce distinguishable surface enhanced Raman scattering (SERS) signals for rapid and long-term authentication. In this study, the stability and invisibility of the nanotags on tablets were investigated, and successful authentication of tablets stored for over 8 years was achieved.
ADVANCED MATERIALS INTERFACES
(2023)
Article
Chemistry, Applied
Alexandru-Milentie Hada, Monica Potara, Simion Astilean, Annalaura Cordaro, Giulia Neri, Milo Malanga, Antonia Nostro, Antonino Mazzaglia, Angela Scala, Anna Piperno
Summary: In this study, we propose a mild, ecofriendly, and straightforward synthesis method for producing core-shell Au@Ag bimetallic nanoparticles for antibacterial nanomedicine and SERS imaging. The synthesis utilizes a cationic polymeric cyclodextrin as a reducing and stabilizing agent to obtain monodispersed and stable nanoparticles. The resulting nanoparticles show good antibacterial activity and can be used for various applications.
CARBOHYDRATE POLYMERS
(2022)
Review
Chemistry, Multidisciplinary
Gour Mohan Das, Stefano Manago, Maria Mangini, Anna Chiara De Luca
Summary: Surface-enhanced Raman spectroscopy (SERS) is a powerful tool for biosensing applications due to its high sensitivity and multiplex detection capabilities. This review outlines the key aspects of SERS in the biomedical field, including mechanisms, substrates and fabrication methods, performance characterization factors, and applications.
Article
Engineering, Environmental
Daifeng Li, Chi Zhang, Xiaoyan Tai, Denghui Xu, Jianzhong Xu, Pengfei Sun, Quli Fan, Zhen Cheng, Yi Zhang
Summary: This study developed a novel nanoplatform, P2NPs, with strong photothermal therapy and dual-modal optical tracking capabilities. In vitro and in vivo experiments demonstrated the potential of this platform in the treatment of osteosarcoma.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Analytical
Bing Liu, Shiya Zheng, Haitao Li, Junjie Xu, Hanyu Tang, Yi Wang, Yingchao Wang, Fei Sun, Xiangwei Zhao
Summary: The study presents a multiplex strategy based on magnetic nanoparticles and SERS nanotags for rapid and accurate detection of trace antibiotics, showing high sensitivity and multiplexing capabilities.
Article
Chemistry, Physical
Sanggon Kim, Orisson Gomes, Ali Riaz, Mourad Roudjane, Paulo N. Lisboa-Filho, Augusto Batagin-Neto, Younes Messaddeq, Yves De Koninck
Summary: Surface-enhanced Raman spectroscopy (SERS) is a powerful tool in biophysics, bioanalytical chemistry, and biomedicine for monitoring extracellular chemical activity. However, the limited choice of SERS nanotags has hindered its practical application. This study repurposes fluorescent chemosensors as SERS nanotags, using a plasmon-induced reaction to immobilize them onto plasmonic nanostructures. The results demonstrate the successful immobilization and functionality of xanthene-based chemosensors as SERS chemosensors.
SURFACES AND INTERFACES
(2024)
Article
Chemistry, Multidisciplinary
Shangyu Y. Chen, Yonghui H. Pan, Kai Chen, Pengfei F. Chen, Qingming M. Shen, Pengfei F. Sun, Wenbo B. Hu, Quli L. Fan
Summary: By tailoring molecular planarity, researchers have developed a high-performance conjugated small molecule (CSM) that absorbs in the near-infrared II (NIR-II) range for phototheranostic applications. Increasing the number of thiophene units extends the absorption to the NIR-II region, but excessive thiophene units result in decreased brightness and photothermal effects. Introducing a nonconjugated alkyl chain enhances the NIR-II absorption coefficient, brightness, and photothermal effects. This finding provides guidance for the design of NIR-II-absorbing CSMs through rational manipulation of molecular planarity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Physics, Applied
Li Lin, Xinyuan Bi, Yuqing Gu, Fu Wang, Jian Ye
Summary: Surface-enhanced Raman scattering (SERS) technique, with the implementation of SERS nanotags, has opened up new possibilities for bioimaging and detection of cancer cells and tissues with favorable properties and high spatial resolution.
JOURNAL OF APPLIED PHYSICS
(2021)
Article
Chemistry, Analytical
Qian Yu, Hoa Duc Trinh, Yeonji Lee, Taejoon Kang, Lingxin Chen, Sangwoon Yoon, Jaebum Choo
Summary: In this study, a silica-encapsulated Au core-satellite (CS@SiO2) nanotag was developed, which exhibited strong and reproducible surface-enhanced Raman scattering (SERS) signal. By combining SERS with enzyme-linked immunosorbent assay (ELISA), a highly sensitive detection of SARS-CoV-2 was achieved. The CS@SiO2 nanotags showed superior performance with a detection limit of 8.81 PFU mL-1, which is 10 times better than conventional ELISA and 100 times better than lateral flow assay strip method. The new CS@SiO2-SERS-ELISA method can significantly reduce the false-negative diagnostic rate for SARS-CoV-2 and contribute to overcoming the current pandemic crisis.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Agriculture, Multidisciplinary
Jialong Sun, Wei Li, Xuerui Zhu, Saisai Jiao, Yunwei Chang, Siwei Wang, Shijie Dai, Ruimin Xu, Menghua Dou, Qianjin Li, Jianlin Li
Summary: A novel multiplex mycotoxin surface-enhanced Raman spectroscopy (SERS) immunoassay was established using antigen-modified silica photonic crystal microspheres (SPCMs) and gold nanoparticles (AuNPs) for multiplex detection with high sensitivity and good recovery rates. The method exhibited high specificity and repeatability, while overcoming the drawbacks of fluorescence and chemiluminescence background signals.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2021)
Article
Engineering, Biomedical
Quan Cheng, Youliang Tian, Huiping Dang, Changchang Teng, Kai Xie, Dalong Yin, Lifeng Yan
Summary: A NIR-II macromolecular probe (MPAE) with excellent biocompatibility and resistance to self-quenching has been synthesized, showing superior performance in biological imaging.
ADVANCED HEALTHCARE MATERIALS
(2022)
Article
Chemistry, Analytical
Aristea Anna Leventi, Kharmen Billimoria, Dorota Bartczak, Stacey Laing, Heidi Goenaga-Infante, Karen Faulds, Duncan Graham
Summary: Researchers developed a new quantitation model to calibrate the SERS response against the absolute concentration of SERS nanotags using spICP-MS, and demonstrated a homogeneous distribution and linear response of the nanotags in gelatin standards using laser ablation inductively coupled plasma time-of-flight mass spectrometry imaging. This novel calibration model shows the potential for quantitative SERS imaging, allowing correlation of nanoparticle concentration to biological responses for better understanding of disease models.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Ewan W. Hislop, William J. Tipping, Karen Faulds, Duncan Graham
Summary: This study combines hyperspectral stimulated Raman scattering (SRS) microscopy with advanced chemometrics to provide a label-free spatiotemporal map of mitosis, offering insights into the intrinsic biomolecular properties of this essential process in mammalian life.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Henry J. Braddick, William J. Tipping, Liam T. Wilson, Harry S. Jaconelli, Emma K. Grant, Karen Faulds, Duncan Graham, Nicholas C. O. Tomkinson
Summary: This article reports the first ratiometric sensor for carboxylesterase (CE) activity using Raman spectroscopy based on a bisarylbutadiyne scaffold. The sensor showed high sensitivity and specificity for CE detection with low cellular cytotoxicity. It was successfully used for ratiometric detection of esterase activity in hepatocyte cells and detection of localized ultraviolet damage in a mixed cell population using stimulated Raman scattering microscopy coupled with spectral phasor analysis.
ANALYTICAL CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Jean-Francois Masson, Gregory Q. Wallace, Jeremie Asselin, Andrey Ten, Maryam Hojjat Jodaylami, Karen Faulds, Duncan Graham, John S. Biggins, Emilie Ringe
Summary: Curved surfaces with a radius of around 5 μm can enhance optoplasmonic properties, such as surface-enhanced Raman scattering (SERS), photocatalysis, and photothermal processes. The plasmonic effects are maximized for spherical objects with a diameter of a few micrometers.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Neville Murphy, William J. Tipping, Henry J. Braddick, Liam T. Wilson, Nicholas C. O. Tomkinson, Karen Faulds, Duncan Graham, Pau Farras
Summary: This study reports the application of spectral phasor analysis to unmix three bioorthogonal Raman probes in live cells. Triplex detection of a metallacarborane, a bis-alkyne, and a deuterated fatty acid can be achieved within the cell-silent region of the Raman spectrum. Additionally, nine regions of interest can be spectrally unmixed from the hyperspectral dataset, offering a new capability for multiplexed Raman imaging of live cells.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Analytical
Samantha M. M. McCabe, Gregory Q. Q. Wallace, Sian Sloan-Dennison, William J. J. Tipping, Neil C. C. Shand, Duncan Graham, Marie Boyd, Karen Faulds
Summary: This study investigates the uptake and distribution of silica coated gold nanoparticles (AuNP-SHINs) in three-dimensional multicellular tumour spheroids derived from glioblastoma cells. The results show that the localization of nanoparticles within the spheroids is influenced by factors such as size, quiescence, and hypoxia.
Article
Chemistry, Multidisciplinary
Aristea Anna Leventi, Henry J. Braddick, Kharmen Billimoria, Gregory Q. Wallace, Heidi Goenaga-Infante, Nicholas C. O. Tomkinson, Karen Faulds, Duncan Graham
Summary: This article reports the synthesis of nanocarriers for delivering the antitumor drug cisplatin. Multimodal imaging techniques, including surface enhanced Raman scattering and laser ablation inductively coupled plasma time of flight mass spectrometry, were used to visualize the intracellular uptake of both the nanocarrier and drug.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Analytical
Iona E. Hill, Marie Boyd, Kirsty Milligan, Cerys A. Jenkins, Annette Sorensen, Andrew Jirasek, Duncan Graham, Karen Faulds
Summary: Radiation therapy is widely used in cancer treatment, but there are large variations in treatment responses due to the heterogeneity of cancer. This study evaluated the potential of Raman spectroscopy for monitoring cellular response to radiation in specific cell cycle phases. The results showed that Raman spectroscopy combined with cell cycle and DNA damage analysis could discriminate the subtle cellular changes associated with radiation response.
Article
Chemistry, Analytical
Aurelie Rensonnet, William J. Tipping, Cedric Malherbe, Karen Faulds, Gauthier Eppe, Duncan Graham
Summary: Hyperspectral stimulated Raman scattering (SRS) microscopy combined with spectral phasor analysis is a powerful method for the detection of fatty acids in solution and in cellular lipid droplets.
Article
Chemistry, Analytical
Yichen Zhao, Nikesh Patel, Peihuan Sun, Karen Faulds, Duncan Graham, Juewen Liu
Summary: Due to their programmable structures, aptamers can retain their target binding function even when split into two halves. Comparisons between split aptamers and full-length aptamers showed that split aptamers with longer stem lengths had similar dissociation constants to the full-length aptamer, while a shorter stem construct had a much higher dissociation constant. Temperature-dependent fluorescence measurements and isothermal titration calorimetry confirmed the lower thermodynamic stability of split aptamers.
Article
Chemistry, Analytical
Yichen Zhao, Nikesh Patel, Peihuan Sun, Karen Faulds, Duncan Graham, Juewen Liu
Summary: Split aptamers, which can be divided into two halves while retaining their target binding function, have been widely used in biosensors. However, there is still a lack of fundamental studies on their binding. In this study, a new aptamer called OTC5 was used to compare different split aptamers with the full-length aptamer. It was found that split aptamers with longer stem lengths showed similar binding properties to the full-length aptamer, while a shorter stem construct had a significantly lower binding affinity. Temperature-dependent fluorescence measurements and isothermal titration calorimetry further confirmed the differences in stability and binding thermodynamics of split aptamers.
Article
Nanoscience & Nanotechnology
Jean-Francois Masson, Gregory Q. Wallace, Jeremie Asselin, Andrey Ten, Maryam Hojjat Jodaylami, Karen Faulds, Duncan Graham, John S. Biggins, Emilie Ringe
Summary: The study demonstrates that surface curvature can enhance optoplasmonic properties, especially for spherical surfaces with a diameter of around 5 micrometers. The findings have significant implications for the development of next-generation sensors, plasmonic photocatalysts, and photothermal devices.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Sergey Yu. Ketkov, Sheng-Yuan Tzeng, Elena A. Rychagova, Anton N. Lukoyanov, Wen-Bih Tzeng
Summary: Metallocenes, including methylcobaltocene, play important roles in various fields of chemistry. The ionization energy and vibrational structure of (Cp ')(Cp)Co can be influenced by introducing methyl substituents. The mass-analyzed threshold ionization spectrum and DFT calculations provide accurate information about the properties and transformations of (Cp ')(Cp)Co.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Review
Chemistry, Physical
Qifeng Mu, Jian Hu
Summary: Polymer mechanochemistry has experienced a renaissance due to the rapid development of mechanophores and principles governing mechanochemical transduction or material strengthening. It has not only provided fundamental guidelines for converting mechanical energy into chemical output, but also found applications in engineering and smart devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Vikki Anand Varma, Simmie Jaglan, Mohd Yasir Khan, Sujin B. Babu
Summary: Designing engineering structures like nanocages, shells, and containers through self-assembly of colloids is a challenging problem. This work proposes a simple model for the subunit, which leads to the formation of monodispersed spherical cages or containers. The model with only one control parameter can be used to design cages with the desired radius.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Hainan Jiang, Yaolong He, Xiaolin Li, Zhiyao Jin, Huijie Yu, Dawei Li
Summary: The cycling lifespan and coulombic efficiency of lithium-ion batteries are crucial for high C-rate applications. The Li-ion concentration plays a crucial role in determining the mechanical integrity and structural stability of electrodes. This study focuses on graphite as the working electrode and establishes an experimental system to investigate the mechanical properties of composite graphite electrode at different C-rates. Considering the effect of Li-ion concentration in stress analysis is found to be significant.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Zhiye Wang, Yunchuan Li, Mingjun Sun
Summary: This study investigates the influence of intramolecular pi-pi interactions on the electronic transport capabilities of molecules. By designing and analyzing three pi-conjugated molecules, the researchers observe that different pi-conjugated structures have varying effects on electron transport. The findings provide a theoretical foundation for designing single-molecule electronic devices with multiple electron channels based on intramolecular pi-pi interactions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Yuandong Xu, Haoyang Feng, Chaoyang Dong, Yuqing Yang, Meng Zhou, Yajun Wei, Hui Guo, Yaqing Wei, Jishan Su, Yingying Ben, Xia Zhang
Summary: Hollow MoS2 cubes and spheres were successfully synthesized using a one-step hydrothermal method with the hard template method. The hollow MoS2 cubes exhibited higher specific capacitance and energy density compared to the hollow MoS2 spheres. The symmetrical supercapacitors assembled with these hollow structures showed good performance and high capacity retention after multiple cycles. These findings suggest that controlling the pore structure and surface characteristics of MoS2 is crucial for enhancing its electrochemical properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Ainhoa Oliden-Sanchez, Rebeca Sola-Llano, Joaquin Perez-Pariente, Luis Gomez-Hortiguela, Virginia Martinez-Martinez
Summary: The combination of photoactive molecules and inorganic structures is important for the development of advanced materials in optics. In this study, bulky dyes were successfully encapsulated in a zeolitic framework, resulting in emission throughout the visible spectrum.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Miaomiao Zhang, Cunyuan Pei, Qiqi Xiang, Lintao Liu, Zhongxu Dai, Huijuan Ma, Shibing Ni
Summary: The design of a solid electrolyte interphase (SEI) plays a crucial role in improving the electrochemical performance of anode materials. In this study, lithium difluoro(oxalate)borate (LiDFOB) is used as an electrolyte additive to form a protective SEI film on Li3VO4 (LVO) anodes. The addition of LiDFOB results in a dense, uniform, stable, and LiF-richer SEI, which enhances the Li-ion storage kinetics. The generated SEI also prevents further decomposition of the electrolyte and maintains the morphology of LVO anodes during charge/discharge processes. This work demonstrates the effectiveness of LiDFOB as a multi-functional additive for LiPF6 electrolytes and provides insights into SEI construction for high-performance LVO anodes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
B. V. Andryushechkin, T. V. Pavlova, V. M. Shevlyuga
Summary: The atomic structure of the Ag(111)-p(4 x 4)-O phase was reexamined and two phases with the same periodicity were discovered. It was demonstrated that the accepted Ag6 model is incompatible with high-resolution oxygen-sensitive STM images.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
S. L. Romo-Avila, D. Marquez-Ruiz, R. A. Guirado-Lopez
Summary: In this study, we used density functional theory (DFT) calculations to investigate the interaction between model graphene oxide (GO) nanostructures and chlorine monoxide ClO. We aimed to understand the role of this highly oxidizing species in breaking C-C bonds and forming significant holes on GO sheets. Our results showed that C-C bonds in a single graphene oxide sheet can be broken through a simple mechanism involving the dissociation of two chemically attached ClO molecules. The formation of carbonyl groups and holes on the GO surface was also observed. This study provides important insights into the degradation of carbon nanotubes and the stability of GO during the myeloperoxidase (MPO) catalytic cycle.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Alberto Garcia-Fernandez, Birgit Kammlander, Stefania Riva, Hakan Rensmo, Ute B. Cappel
Summary: In this study, the X-ray stability of five different lead halide perovskite compositions (MAPbI3, MAPbCl3, MAPbBr3, FAPbBr3, CsPbBr3) was investigated using photoelectron spectroscopy. Different degradation mechanisms and resistance to X-ray were observed depending on the crystal composition. Overall, perovskite compositions based on the MA+ cation were found to be less stable than those based on FA+ or Cs+. Metallic lead formation was most easily observed in the chloride perovskite, followed by bromide, and very little in MAPbI3. Multiple degradation processes were identified for the bromide compositions, including ion migration, formation of volatile and solid products, as well as metallic lead. CsBr was formed as a solid degradation product on the surface of CsPbBr3.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Timofei Rostilov, Vadim Ziborov, Alexander Dolgoborodov, Mikhail Kuskov
Summary: The shock-loading behavior of nanomaterials is investigated in this study. It is found that shock compaction waves exhibit a distinct two-step structure, with the formation of faster precursor waves that travel ahead of the main compaction waves. The complexity of the shock Hugoniot curve of the tested nanomaterial is described, and the effect of initial porosity on the compressed states is demonstrated.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Sergey S. Nikitin, Alexander D. Koryakov, Elizaveta A. Antipinskaya, Alexey A. Markov, Mikhail V. Patrakeev
Summary: The stability of La1/3Sr2/3Fe1-xMnxO3-delta, a perovskite-type oxide, under reducing conditions is dependent on the manganese content. Increasing the manganese content leads to a decrease in stability. The behavior of iron and manganese in the oxide shows distinct differences, which can be attributed to the difference in the enthalpy of oxidation reactions. Additionally, the change in the La/Sr ratio affects the concentration of iron and manganese ions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Mosayeb Naseri, Shirin Amirian, Mehrdad Faraji, Mohammad Abdur Rashid, Maicon Pierre Lourenco, Venkataraman Thangadurai, D. R. Salahub
Summary: Inspired by the successful transfer of freestanding ultrathin films of SrTiO3 and BiFeO3, this study assessed the structural stability and investigated the electronic, optical, and thermoelectric properties of a group of two-dimensional perovskite-type materials called perovskenes. The findings revealed that these materials are wide bandgap semiconductors with potential application in UV shielding. Moreover, they exhibit better electrical and thermal conductivity at high temperatures, enabling efficient power generation in thermoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)