4.7 Article Proceedings Paper

Relation between substrate surface morphology and microcrystalline silicon solar cell performance

Journal

JOURNAL OF NON-CRYSTALLINE SOLIDS
Volume 354, Issue 19-25, Pages 2258-2262

Publisher

ELSEVIER
DOI: 10.1016/j.jnoncrysol.2007.09.084

Keywords

silicon; solar cells; photovoltaics; TEM/STEM; microcrystallinity; porosity

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In the present paper, the structural and electrical performances of microcrystalline silicon (mu c-Si:H) single junction solar cells co-deposited on a series of substrates having different surface morphologies varying from V-shaped to U-shaped valleys, are analyzed. Transmission electron microscopy (TEM) is used to quantify the density of cracks within the cells deposited on the various substrates. Standard 1 sun, variable illumination measurements (VIM) and Dark J(V) measurements are performed to evaluate the electrical performances of the devices. A marked increase of the reverse saturation current density (J(0)) is observed for increasing crack densities. By introducing a novel equivalent circuit taking into account such cracks as non-linear shunts, the authors are able to relate the magnitude of the decrease of V-oc and FF to the increasing density of cracks. (c) 2007 Elsevier B.V. All rights reserved.

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