Journal
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
Volume 212, Issue 10, Pages 2162-2168Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssa.201532040
Keywords
excitons; MoO3; organic solar cells; PCDTBT; photocrosslinking
Funding
- Bavarian State Ministry of Science, Research, and the Arts through Collaborative Research Network Solar Technologies go Hybrid
- German Science Foundation DFG through doctoral training center [GRK 1640]
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We show that the performance of an organic solar cell can be increased by the introduction of an additional polymeric exciton blocking layer. In order to realize this, the novel polymer PFTPDAc with pendant acrylate groups is developed. Thin films are coated from a PFTPDAc solution and subsequently crosslinked by irradiation. Thereby, the film becomes completely insoluble and allows spincoating of a second polymer layer on top. We realize a three layer solar cell which contains a crosslinked PFTPDAc interlayer on top of the molybdenum oxide anode and layers of the low-bandgap polymer PCDTBT and C-60. In comparison with a reference cell without the interlayer, the EQE is significantly increased in the spectral region between 400 and 650 nm. From current-voltage measurements a power conversion efficiency of 1.8% is determined. PL measurements show that the increase of solar cell performance is attributed to exciton blocking by the PFTPDAc interlayer.
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