Journal
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume 14, Issue 10, Pages 7870-7873Publisher
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2014.9442
Keywords
Photocurability; Solution-Process; Silica-Nanoparticle; Acryl; Hybrid
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Solventless silica-acryl hybrid materials composed of organically modified silica nanoparticles and acryl monomers were fabricated using a simple sol-gel process and solvent evaporation. The homogeneously dispersed silica-acryl hybrid materials can be formed into films through a simple solution-coating process and UV curing. The silica-acryl hybrid materials exhibited good photocurability with similar to 90% conversion upon UV exposure and a high transmittance of above 95% in the visible wavelength region regardless of the silica nanoparticle content. In particular, the silica-acryl hybrid materials exhibited increased mechanical hardness and thermal stability directly proportional to the content of silica nanoparticles and exhibited a good surface roughness of similar to 1 nm. Therefore, these silica-acryl hybrid materials are good candidates for coating applications in electronic, electro-optic, and energy devices.
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