Article
Environmental Sciences
Santanu Mukherjee, Alok Kumar Thakur, Ritusmita Goswami, Payal Mazumder, Kaling Taki, Meththika Vithanage, Manish Kumar
Summary: The study investigated the use of rice straw derived biochar for arsenic (V) removal from aqueous medium, showing high adsorption capacity and efficiency. Optimal parameters were determined through batch experiments, and future research will focus on treating wastewater samples containing mixtures of contaminants and real case scenarios of biopurification studies using biofilter beds containing different spent adsorbents/organic substrates.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Chemistry, Multidisciplinary
Fozia Bibi, Rafaqat Hussain, Naseem Iqbal, Shaukat Saeed, Muhammad Waseem, Eslam B. Elkaeed, Murefah Mana Al-Anazy, Sirajul Haq
Summary: This study synthesized magnetic activated carbon (MAC) as an efficient adsorbent material using the hydrothermal method. The adsorption behavior of As(III) onto MAC was examined, and it was found that MCNa had a removal efficiency of 99%. The pseudo 2nd-order kinetics and Langmuir model were applicable to the adsorption process.
ARABIAN JOURNAL OF CHEMISTRY
(2023)
Article
Engineering, Environmental
Mehran Aliaskari, Andrea Schaefer
Summary: This study investigated the impact of operational and water quality parameters on brackish water decontamination using a batch electrodialysis (ED) system. The results showed the significance of ionic characteristics in ED, with nitrate concentrations satisfying guideline threshold in all experiments. Lowest arsenic(V) concentration was 35 mu g/L at the highest electric potential, 25 V, demonstrating the potential of ED in environmentally friendly processes.
Article
Environmental Sciences
Tonoy K. Das, Achintya N. Bezbaruah
Summary: The study compared graphene oxide supported magnetite (GM) and graphene oxide supported nanoscale zero-valent iron (GNZVI) nanohybrids for arsenic removal and found GNZVI to be more efficient across a wider pH range compared to GM. GNZVI also demonstrated better aqueous dispersibility and higher efficiency for arsenic removal compared to GM.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Review
Engineering, Chemical
A. Saravanan, P. R. Yaashikaa, P. Senthil Kumar, S. Karishma, P. Thamarai, V. C. Deivayanai, Gayathri Rangasamy, Rangabhashiyam Selvasembian, Tejraj M. Aminabhavi
Summary: In recent times, the removal of arsenic from wastewater has become crucial due to its persistence and bioaccumulation, which cause serious health and environmental issues. The electrodeionization (EDI) technique, utilizing hybrid electrodialysis/ion exchange, is reviewed as a sustainable approach for detoxifying wastewater by eliminating toxic arsenic. The EDI process employs anion/cation exchange resins that are efficiently regenerated by an electric current, leading to a significant reduction in water ions. The study discusses module configuration, performance optimization, ion separation mechanism, and recent advances in utilizing EDI for the removal/recovery of toxic arsenic.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
Amal Kanti Deb, Bhabananda Biswas, Mohammad Mahmudur Rahman, Yunfei Xi, Santosh Kumar Paul, Ravi Naidu
Summary: This study presents the ecofriendly synthesis of magnetite nanoparticles (Fe3O4 NPs)-immobilized halloysite nanotube (HNT) composite (Fe3O4@ HNT) for remediating arsenate [As(V)] from water. Fe3O4@HNT was easily separable by an external magnet and showed excellent efficiency in removing As(V) from groundwater. The material was also cost-effective, reusable, and biocompatible, making it a prospective composite for the sustainable eradication of arsenic and other metallic toxicants from wastewater.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Doina Humelnicu, Maria Ignat, Maria Valentina Dinu, Ecaterina Stela Dragan
Summary: This paper reports on the performance of cross-linked amidoxime hosted into mesoporous silica (AMOX) for the removal of As(III) and As(V). The optimal pH for sorption of As(III) and As(V) were found to be pH 8 and pH 5, respectively. The kinetic model and isotherm analysis showed good fit with the experimental data. Thermodynamic parameters revealed that the adsorption process of As(III) and As(V) was spontaneous and endothermic on all AMOX sorbents. Furthermore, the spent AMOX sorbents could be easily regenerated and reused multiple times. The adverse effect of co-existing inorganic anions on the adsorption of As(III) and As(V) was also evaluated.
Article
Chemistry, Multidisciplinary
Qian Zhang, Dan Zheng, Bo Bai, Meng Mei, Feiying Yang
Summary: The use of pyrite waste for photothermal conversion and heat energy storage can improve solar energy utilization and enhance pollutant removal efficiency in environmental governance.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Engineering, Environmental
Tianya Dai, Jinpeng Feng, Jiann-Yang Hwang, Yangyang Bao, Chenhui Gao, Zeping Wang, Wei Mo, Xiujuan Su, Hongfei Lin
Summary: A novel high-efficiency vermiculite/zinc hexacyanoferrate (II) (VMT/ZnHCF) composite adsorbent was prepared to solve the problems of low adsorption capacity, complex preparation, and difficult recovery for reported cesium ion adsorbents. The composite exhibited a maximum Cs+ adsorption capacity of 378.79 mg/g, which was significantly higher than other absorbents. The Cs+ adsorption mechanism was revealed to be synergistically achieved through the ion exchange of Na+ in vermiculite interlayers and Zn2+ in zinc hexacyanoferrate (II) lattices, as analyzed by ion exchange experiments and characterization techniques.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Materials Science, Ceramics
Farida khan, A. Naeem, Israf Ud Din, T. Saeed, Mshari A. Alotaibi, Abdulrahman I. Alharthi, Asad Habib, Tabassum Malik
Summary: In this study, hexagonal boron nitride (h-BN) was synthesized and used as an efficient sorbent for the uptake of Cd2+ ions. The kinetics and sorption studies showed that the process of Cd2+ sorption remained endothermic, and the Ho's model was found to best interpret the adsorption kinetic data. The physicochemical properties of h-BN were characterized before and after adsorption, showing its effectiveness as an adsorbent for Cd2+ ions in aqueous media.
CERAMICS INTERNATIONAL
(2021)
Article
Environmental Sciences
Raquel D. Almeida, Juacyara C. Campos, Mariana M. V. M. Souza
Summary: The study found that hydrocalumites and calcined hydrocalumite have good potential in reducing the fluoride content in aqueous solutions, with the main removal mechanisms being ion exchange and adsorption.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Tao Yu, Yiliang Chen, Yizhong Zhang, Xin Tan, Tao Xie, Boyu Shao, Xiang Huang
Summary: The study presented millimeter-sized sulfate-type zirconium alginate hydrogel beads with high adsorption capacity and wide pH applicability, showing potential application in treating fluoride-containing groundwater. The ion exchange process between SO42- and F- in the material was energetically favorable, as verified through various analytical techniques.
CHINESE CHEMICAL LETTERS
(2021)
Article
Engineering, Chemical
Mehran Aliaskari, Ramatisa L. Ramos, Andrea Schaefer
Summary: In this study, the removal of arsenic and selenium from brackish water using a batch electrodialysis system was investigated. The results showed that the removal of these elements was influenced by pH and salinity, with higher concentrations leading to higher removal rates. Electromigration transport was found to be the dominant mechanism, and the ionic characteristics played a key role in the removal process. Real contaminated groundwater samples also demonstrated the potential of electrodialysis for selective removal of more mobile ions.
Article
Chemistry, Multidisciplinary
Sarangerel Davaasambuu, Delgersaikhan Chuluunsukh, Altangerel Amarsanaa
Summary: Complex solid residuals can form during the electrocoagulation of arsenic from aqueous media based on the characteristics of the electrochemical system and cooccurring processes. The composition and behaviors of these residuals were studied in this research, revealing the formation of different minerals depending on the pH of the solution. The study also showed that adsorption and chemical precipitation occurred simultaneously during the electrocoagulation of arsenic in aqueous media.
Review
Engineering, Environmental
Lukasz Stala, Justyna Ulatowska, Izabela Polowczyk
Summary: Pollution by heavy metal ions in aqueous systems has gradually gained researchers' attention. Technologies such as chemical precipitation, adsorption, membrane filtration, and ion exchange have been developed for ion removal, with a focus on materials like polyampholytes. Recent publications show promising properties of experimental polyampholytes in toxic metal ion removal, encouraging further research in this area.
Article
Nanoscience & Nanotechnology
B. Palanisamy, C. M. Babu, B. Sundaravel, K. Shanthi, V. Murugesan
SCIENCE OF ADVANCED MATERIALS
(2015)
Article
Nanoscience & Nanotechnology
C. M. Babu, B. Palanisamy, B. Sundaravel, K. Shanthi, V. Murugesan
SCIENCE OF ADVANCED MATERIALS
(2015)
Article
Engineering, Chemical
Balachandran Sundaravel, Cadiam Mohan Babu, Rajangam Vinodh, Wang Seog Cha, Hyun-Tae Jang
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2016)
Article
Engineering, Chemical
Cadiam Mohan Babu, Rajangam Vinodh, Balachandran Sundaravel, Aziz Abidov, Mei Mei Peng, Wang Seog Cha, Hyun-Tae Jang
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2016)
Article
Engineering, Environmental
B. Palanisamy, C. M. Babu, B. Sundaravel, S. Anandan, V. Murugesan
JOURNAL OF HAZARDOUS MATERIALS
(2013)
Article
Chemistry, Multidisciplinary
B. Sundaravel, C. M. Babu, B. Palanisamy, M. Palanichamy, K. Shanthi, V. Murugesan
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
(2013)
Article
Chemistry, Multidisciplinary
R. Visuvamithiran, B. Sundaravel, M. Palanichamy, V. Murugesan
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
(2013)
Article
Chemistry, Multidisciplinary
B. Palanisamy, C. M. Babu, B. Sundaravel, S. Anandan, V. Murugesan
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
(2013)
Article
Chemistry, Multidisciplinary
S. Devika, B. Sundaravel, M. Palanichamy, V. Murugesan
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
(2014)
Article
Nanoscience & Nanotechnology
Azhagapillai Prabhu, Venugopal Sudha, Muthusamy Poomalai Pachamuthu, Balachandran Sundaravel, Stefano Bellucci
Summary: This study investigates the synthesis of Al-SBA-15 catalysts using ultrasonic irradiation and their catalytic activity in the tert-butylation reaction. The results show that the catalysts synthesized using ultrasonic irradiation exhibit a well-ordered hexagonal mesoporous structure and high product selectivity.
JOURNAL OF NANOMATERIALS
(2022)
Article
Chemistry, Physical
Karthikeyan Gopalsamy, Sathishkannan Radhakrishnan, Sundaravel Balachandran, Prabhu Azhagapillai
Summary: In this study, Co3O4 and alkali metal-doped Co3O4 spinel materials were prepared and used as catalysts for CO oxidation. The synthesized materials were characterized, and it was found that alkali metal ions can enhance the catalytic activity of Co3O4 materials, especially Li ions. The influence of surface properties of alkali ion-doped Co3O4 spinel catalysts on the reactivity toward CO oxidation was investigated.
SURFACES AND INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
B. Sundaravel, C. M. Babu, B. Palanisamy, M. Palanichamy, V. Murugesan
ADVANCED POROUS MATERIALS
(2014)
Article
Chemistry, Applied
Kandan Venkatachalam, Pitchai Visuvamithiran, Balachandran Sundaravel, Muthiapillai Palanichamy, Velayutham Murugesan
CHINESE JOURNAL OF CATALYSIS
(2012)