4.4 Article

Nanofiltration membranes based on polyvinylidene fluoride nanofibrous scaffolds and crosslinked polyethyleneimine networks

Journal

JOURNAL OF NANOPARTICLE RESEARCH
Volume 14, Issue 7, Pages -

Publisher

SPRINGER
DOI: 10.1007/s11051-012-0884-7

Keywords

Nanofibers; Polyethylenimine; Polyvinylidene fluoride; Hyperbranched; Polymer networks; Membranes; Nanofiltration; Water purification; Nanotechnology sustainable development

Funding

  1. EEWS Initiative [NT080607C0209721]
  2. U.S National Science Foundation (NSF) [0948485]
  3. KAIST World Class University (WCU) program [NRF-31-2008-000-10055]
  4. Div Of Chem, Bioeng, Env, & Transp Sys
  5. Directorate For Engineering [0948485] Funding Source: National Science Foundation
  6. Ministry of Education, Science & Technology (MoST), Republic of Korea [N01120018] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  7. National Research Foundation of Korea [과C6A2402] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

Ask authors/readers for more resources

In this article, we describe the synthesis of new and ion-selective nanofiltration (NF) membranes using polyvinylidene fluoride (PVDF) nanofibers and hyperbranched polyethylenimine (PEI) as building blocks. These new nanofibrous composite (NFC) membranes consist of crosslinked hyperbranched PEI networks supported by PVDF nanofibrous scaffolds that are electrospun onto commercial PVDF microfiltration (MF) membranes. A major objective of our study was to fabricate positively charged NF membranes that can be operated at low pressure with high water flux and improved rejection for monovalent cations. To achieve this, we investigated the effects of crosslinker chemistry on membrane properties (morphology, composition, hydrophobicity, and zeta potential) and membrane performance (salt rejection and permeate flux) in aqueous solutions (2,000 mg/L) of four salts (NaCl, MgCl2, Na2SO4, and MgSO4) at pH 4, 6, and 8. We found that an NFC-PVDF membrane with a network of PEI macromolecules crosslinked with trimesoyl chloride has a high water flux (similar to 30 L m(-2) h(-1)) and high rejections for MgCl2 (similar to 88 %) and NaCl (similar to 65%) at pH 6 using a pressure of 7 bar. The overall results of our study suggest that PVDF nanofibers and hyperbranched PEI are promising building blocks for the fabrication of high performance NF membranes for water purification.

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