☆ 4.6 Article

Bis(4-chloroanilinum) trimolybdate - Synthesis and structural studies of a new polymolybdate material

JOURNAL OF MOLECULAR STRUCTURE (2010)

Journal

JOURNAL OF MOLECULAR STRUCTURE

Volume 965, Issue 1-3, Pages 131-136

Publisher

ELSEVIER

DOI: 10.1016/j.molstruc.2009.11.054

Keywords

Polymolybdates; Structure determination from powder data; Rietveld method; Thermal decomposition studies

Categories

Chemistry, Physical

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Abstract

New polymolybdate: bis(4-chloroanilinum) trimolybdate was obtained and its crystal structure was determined using X-ray powder diffraction methods. The compound crystallizes in the monoclinic system and P2(1)/c(14) space group; a = 15.3575(4). b = 7.5891(3), c = 17.7678(3)angstrom, beta=101.722(2)degrees, V = 2027.64(9) angstrom(3). The crystal structure determination was performed from powder diffraction data using both global optimization and direct methods. Synthesis and results of the structure determination, IR and thermal decomposition studies are presented and discussed. (C) 2009 Elsevier B.V. All rights reserved.

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