Article
Chemistry, Multidisciplinary
Vasilii S. Kolmogorov, Alexander S. Erofeev, Emily Woodcock, Yuri M. Efremov, Aleksei P. Iakovlev, Nikita A. Savin, Anna V. Alova, Svetlana V. Lavrushkina, Igor I. Kireev, Alexandra O. Prelovskaya, Elena V. Sviderskaya, Denis Scaini, Natalia L. Klyachko, Peter S. Timashev, Yasufumi Takahashi, Sergey V. Salikhov, Yuri N. Parkhomenko, Alexander G. Majouga, Christopher R. W. Edwards, Pavel Novak, Yuri E. Korchev, Petr V. Gorelkin
Summary: A high-resolution estimation method for mechanical properties and the possibility of qualitative and quantitative analysis of living cells have been demonstrated in this study. Forces applied using a nanopipette are much smaller than those using atomic force microscopy, with no detectable effect on live cells.
Article
Chemistry, Analytical
Yasufumi Takahashi, Yuya Sasaki, Takeshi Yoshida, Kota Honda, Yuanshu Zhou, Takafumi Miyamoto, Tomoko Motoo, Hiroki Higashi, Andrew Shevchuk, Yuri Korchev, Hiroki Ida, Rikinari Hanayama, Takeshi Fukuma
Summary: Scanning ion conductance microscopy (SICM) is a promising tool for visualizing the dynamics of nanoscale cell surface topography. However, the lack of guidelines for fabricating nanopipettes with ideal shape has hindered SICM imaging at the submicron scale. In this study, we developed a simple and reproducible method for fabricating nanopipettes with sub-20nm apertures and demonstrated improved spatial resolution for nanoscale time-lapse topographic imaging.
ANALYTICAL CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Hangbo Zhou, Zhun-Yong Ong, Gang Zhang, Yong-Wei Zhang
Summary: This review examines recent advances in quantum interfacial thermal transport, focusing on the role of the Atomistic Green's Function method in predicting interfacial thermal conductance and discussing the mechanisms and ways to tune the interfacial thermal conductance.
Article
Geochemistry & Geophysics
Ailong Ma, Wen Zhou, Mi Song, Yanfei Zhong
Summary: This article proposes a multiobjective memetic spatiotemporal SPM (MOMSPM) framework that combines the abundance, spatial, and temporal information through a multiobjective optimization approach. It utilizes a global multiobjective search method and two single-objective local search operators to optimize the three objective functions simultaneously. Experimental results on synthetic and real datasets demonstrate the superiority of the proposed method over state-of-the-art spatiotemporal SPM methods.
IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING
(2023)
Article
Chemistry, Physical
Zhuoling Jiang, Kah-Meng Yam, Na Guo, Lishu Zhang, Lei Shen, Chun Zhang
Summary: By using the newly proposed steady-state DFT method, it was discovered that there exists a novel non-equilibrium effect in silane junctions, which can quickly drive thiol-terminated silanes from equilibrium to non-equilibrium states, overturning the previous standard DFT method.
NANOSCALE HORIZONS
(2021)
Article
Chemistry, Multidisciplinary
Timothy Brown, Philip James Blowey, Jack Henry, Adam Sweetman
Summary: The acquisition of dense, three-dimensional, force fields with intramolecular resolution via noncontact atomic force microscopy (NC-AFM) has significantly advanced our understanding of molecular and two-dimensional materials on an atomic scale. Previous intramolecular force mapping was limited to cryogenic temperatures, but this study demonstrates high-resolution, three-dimensional force mapping of a single organic molecule at room temperature by using semiconducting materials to inhibit molecular diffusion and creating robust tip apexes, along with feedforward correction to overcome thermal drift challenges. The results obtained are comparable to those acquired at low temperature, enabling quantitative analysis of the adsorption-induced changes in molecular geometry at the picometer level.
Article
Biochemical Research Methods
Anton V. Chizhov, Lyle J. Graham
Summary: Theoretical approaches to studying neuronal networks can be categorized into biophysically-detailed models and increasingly abstract reduced models. This study presents a systematic procedure to map models of varying complexity across a hierarchy, applied to the primary visual cortex of mammals. By using this approach, the impact of specific biological parameters on network behavior can be clearly identified, showing how simplifications for mathematical convenience can fundamentally alter neural network behavior.
PLOS COMPUTATIONAL BIOLOGY
(2021)
Article
Nanoscience & Nanotechnology
Pascal Gehring, Jakub K. Sowa, Chunwei Hsu, Joeri de Bruijckere, Martijn van der Star, Jennifer J. Le Roy, Lapo Bogani, Erik M. Gauger, Herre S. J. van der Zant
Summary: Theoretical studies suggest that mastering the thermocurrent through single molecules can lead to high-efficiency thermoelectric energy harvesters. This can be achieved by adjusting molecule length, optimizing tunnel coupling strength via chemical anchor groups, or creating localized states in the molecule backbone. However, empirical verification is still awaited due to experimental challenges.
NATURE NANOTECHNOLOGY
(2021)
Article
Geriatrics & Gerontology
Natasha M. Smith, Jeremy N. Ford, Arsalan Haghdel, Lidia Glodzik, Yi Li, Debra D'Angelo, Arindam RoyChoudhury, Xiuyuan Wang, Kaj Blennow, Mony J. De Leon, Jana Ivanidze
Summary: This study used Statistical Parametric Mapping (SPM) technique to improve the diagnostic performance of Alzheimer's disease (AD). The results showed that SPM can accurately identify positive scans and has a higher correlation with CSF A beta 42 levels compared to traditional qualitative assessment methods.
FRONTIERS IN AGING NEUROSCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Bilal Barut, Xavier Cantos-Roman, Justin Crabb, Chun-Pui Kwan, Ripudaman Dixit, Nargess Arabchigavkani, Shenchu Yin, Jubin Nathawat, Keke He, Michael D. Randle, Farah Vandrevala, Takeyoshi Sugaya, Erik Einarsson, Josep M. Jornet, Jonathan P. Bird, Gregory R. Aizin
Summary: This study presents an approach to generate on-chip THz signals using nanoscale transistors with specific structural asymmetry. The asymmetry supports plasma-wave amplification, leading to pronounced NDC. The researchers also demonstrate how this feature can persist at high temperatures. These findings are a significant step forward for the development of active components for THz electronics.
Article
Chemistry, Physical
Luca Ornago, Jerry Kamer, Maria El Abbassi, Ferdinand C. Grozema, Herre S. J. van der Zant
Summary: Switching effects play a crucial role in the design and characterization of nanoscale molecular electronics systems. This study investigates the presence of switching events in reference molecular systems and highlights the importance of proper anchoring group selection and comparison with reference compounds in understanding the origin of switching in molecular break junctions.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Taeko Matsukata, Shintaro Ogura, Javier Garcia de Abajo, Takumi Sannomiya
Summary: Free-electron-based spectroscopies can reveal nanoscale optical properties of semiconductor materials and nanophotonic devices. A cathodoluminescence method is demonstrated that can access both excitation and emission spaces at the nanoscale, providing valuable information on previously inaccessible nanoscale optical properties.
Article
Multidisciplinary Sciences
He-Yun Du, Yi-Fan Huang, Deniz Wong, Mao-Feng Tseng, Yi-Hsin Lee, Chen-Hao Wang, Cheng-Lan Lin, Germar Hoffmann, Kuei-Hsien Chen, Li-Chyong Chen
Summary: High spatial resolution techniques such as near-field scanning electrochemical microscopy and redox mapping were used to study heterogeneous charge transfer behavior of layered MoS2 flakes in organic solutions, providing insights into area and layer-dependent reactivity. This study also revealed a band alignment occurring at the liquid-solid interface through detailed analysis of local processes such as band offset and faradaic current confinement.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Ritu Gupta, Jhantu Pradhan, Arabinda Haldar, Chandrasekhar Murapaka, Prakash Chandra Mondal
Summary: The injection of pure spin current into the non-magnetic layer is crucial in spintronics for transmitting and processing data information. By using an electrochemical method, a pyrene oligomer film was prepared to estimate the spin pumping efficiency across the interfaces using broadband ferromagnetic resonance spectra. The research showed a strong spinterface effect at the permalloy-pyrene interfaces, indicating the potential for efficient broadband spin transport in molecular spintronics.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Analytical
Rong Jin, Wenting Zhou, Yanyan Xu, Dechen Jiang, Danjun Fang
Summary: The electrochemical visualization of proteins in the plasma membrane of single fixed cells was achieved with a spatial resolution of 160nm using scanning electrochemical cell microscopy. This was done by tagging the model protein carcinoembryonic antigen (CEA) with a ruthenium complex (Ru(bpy)(3) (2+))-tagged antibody, which exhibited redox peaks in its cyclic voltammetry curves when in contact with the cellular membrane. The uneven distribution of membrane CEAs on the cells was electrochemically visualized based on the potential-resolved oxidation or reduction currents, providing super-resolution study of cells and more biological information.
ANALYTICAL CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Sergei Kalinin, James J. Steffes, Yongtao Liu, Bryan D. Huey, Maxim Ziatdinov
Summary: In this study, domain switching pathways in ferroelectric materials were explored using a variational autoencoder, allowing for the visualization of domain evolution mechanisms and their correlation with the microstructure.
Article
Energy & Fuels
Nafis Iqbal, Dylan J. Colvin, Eric J. Schneller, Tamil S. Sakthivel, Roger Ristau, Bryan D. Huey, Ben X. J. Yu, Jean-Nicolas Jaubert, Alan J. Curran, Menghong Wang, Sudipta Seal, Roger H. French, Kristopher O. Davis
Summary: Reliability and durability tests are crucial in the PV industry to reduce failure risks. This study investigated contact degradation in monocrystalline and multicrystalline PV modules, finding different darkening patterns and confirming resistive loss mechanism. Material characterization revealed degradation due to metallization corrosion, with differences in darkening pattern attributed to silver paste composition.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Energy & Fuels
Nafis Iqbal, Dylan J. Colvin, Alan J. Curran, Fang Li, Jeya Prakash Ganesan, Dana B. Sulas-Kern, Steven Harvey, Andrew Norman, Joseph Karas, Govindasamy TamizhMani, Jean-Nicolas Jaubert, Parag Banerjee, Bryan D. Huey, Roger H. French, Kristopher O. Davis
Summary: This article discusses the application of multiscale characterization methods in photovoltaic research, including characterization of modules, cells, and materials. These methods can be used to identify the root causes of degradation in photovoltaic systems. Nondestructive characterization techniques and materials characterization techniques are recommended, and the strengths and limitations of each method are discussed.
IEEE JOURNAL OF PHOTOVOLTAICS
(2022)
Article
Energy & Fuels
Xintai Wang, Sara Sangtarash, Angelo Lamantia, Herve Dekkiche, Leonardo Forcieri, Oleg Kolosov, Samuel P. Jarvis, Martin R. Bryce, Colin J. Lambert, Hatef Sadeghi, Benjamin J. Robinson
Summary: In this study, an alternative strategy for enhancing the thermoelectric performance of molecular thin-films is demonstrated. By controlling the thickness of the films and using pi-pi stacking, the Seebeck coefficient is improved and thermal conductance is reduced.
JOURNAL OF PHYSICS-ENERGY
(2022)
Article
Nanoscience & Nanotechnology
Ramesh Nath, Nicholas A. Polomoff, Jingfeng Song, Thomas J. Moran, Ramamoorthy Ramesh, Bryan D. Huey
Summary: The dynamics of ferroelectric domain switching in a PbZr0.2Ti0.8O3 thin film were studied using piezoresponse force microscopy. The study found that the polarization of the domains followed an S-curve, and the nucleation sites and growth patterns showed repeatability. By analyzing the activation energy ratio, it was discovered that using higher poling fields can activate more nucleation sites, enabling faster and more efficient switching.
ADVANCED ELECTRONIC MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Giorgos Antoniou, Nathan R. Halcovitch, Marta Mucientes, William I. Milne, Arokia Nathan, Judith L. MacManus-Driscoll, Oleg V. Kolosov, George Adamopoulos
Summary: This work investigates a solution process for yttria-stabilized zirconia (YSZ) thin film deposition involving the addition of yttria nanoparticles, at 400 degrees C, in air. Different yttrium doping levels in the YSZ were studied and a wide range of optical, structural, surface, dielectric, and electronic transport properties were also investigated. An optimum yttrium doping level of 5% mol. resulted in the smoothest films (R-RMS similar to 0.5 nm), a wide bandgap (similar to 5.96 eV), a dielectric constant in excess of 26, and a leakage current of similar to 0.3 nA cm(-2) at 2 MV/cm. The solution-processed YSZ films were incorporated as gate dielectrics in thin films transistors with solution-processed In2O3 semiconducting channels. Excellent operational characteristics, such as negligible hysteresis, low operational voltages (5 V), electron mobility in excess of 36 cm(2) V-1 s(-1), high on/off current modulation ratio on the order of 10(7), and low interfacial trap density states (< 10(12) cm(-2)), were demonstrated. In addition, excellent film homogeneity was achieved over a large area (16 x 16 cm(2)), with both film thickness and capacitance deviation of < 1.2%.
Article
Chemistry, Multidisciplinary
Erik D. Roede, Konstantin Shapovalov, Thomas J. Moran, Aleksander B. Mosberg, Zewu Yan, Edith Bourret, Andres Cano, Bryan D. Huey, Antonius T. J. van Helvoort, Dennis Meier
Summary: This study demonstrates the importance of nanoscale structure for the emergent transport properties in the 3D network of neutral and charged domain walls in ErMnO3. By using tomographic microscopy techniques and finite element modeling, the contribution of domain walls within the bulk is clarified and the significance of curvature effects for the local conduction is shown down to the nanoscale.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Analytical
Zan Gao, Guangfu Wu, Yang Song, Huijie Li, Yuxuan Zhang, Michael J. Schneider, Yingqi Qiang, Jackson Kaszas, Zhengyan Weng, He Sun, Bryan D. Huey, Rebecca Y. Lai, Yi Zhang
Summary: This study presents a flexible neural probe for multiplexed neurochemical monitoring using aptamers functionalized on graphene field-effect transistors (G-FETs). The neural probes demonstrate excellent flexibility, lightweight, and can monitor serotonin and dopamine with high sensitivity and selectivity. The developed methodology can be adapted for monitoring other neurochemicals.
ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Mujeeb Ahmad, Khushboo Agarwal, Sergio Gonzalez Munoz, Abhishek Ghosh, Nisha Kodan, Oleg Victor Kolosov, Bodh Raj Mehta
Summary: This study reports a significant enhancement of the thermoelectric power factor in Sb2Te3/MoS2 multilayer structures and introduces a new method to determine the thermal conductivity values of nanometer-thick multilayer samples. The findings lay the foundation for the development of novel and viable thermoelectric materials by exploiting the properties of 2D/3D interfaces.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Multidisciplinary Sciences
Jianming Tao, Yue Chen, Aman Bhardwaj, Lang Wen, Jiaxin Li, Oleg V. Kolosov, Yingbin Lin, Zhensheng Hong, Zhigao Huang, Sanjay Mathur
Summary: This study focuses on the incorporation of piezo-/ferroelectric BaTiO3 nanofibers into solid electrolytes and how it affects the growth of Li filaments in solid-state Li-metal batteries. The addition of BaTiO3 nanofibers effectively regulates the nucleation and growth of Li dendrites, leading to improved interfacial stability and safety in the batteries. The experimental results confirm the potential of BaTiO3 as an additive for enhancing the performance and scalability of Li metal anodes in solid-state batteries.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Multidisciplinary
Yifei Wang, Zongze Li, Thomas J. Moran, Luis A. Ortiz, Chao Wu, Antigoni C. Konstantinou, Hiep Nguyen, Jierui Zhou, Jindong Huo, Kerry Davis-Amendola, Peinan Zhou, Bryan D. Huey, Yang Cao
Summary: This study reports a layered nanocomposite with reinforced interfaces for high-temperature high-energy-density dielectrics. By interposing nanocoatings with anisotropic conductivities at different interfaces, the charge injection from the electrode is diminished and the kinetic energy of hot carriers is suppressed. The interface-reinforced nanocomposite achieves ultrahigh energy density and remarkable charge-discharge efficiency at 200 degrees C.
Article
Nanoscience & Nanotechnology
Xintai Wang, Angelo Lamantia, Michael Jay, Hatef Sadeghi, Colin J. Lambert, Oleg Kolosov, Benjamin J. Robinson
Summary: A non-destructive method for probing the electrical and thermoelectric properties of small assemblies of molecules within a self-assembled monolayer (SAM) has been developed. The method combines a modified thermal-electric force microscopy approach with density functional theory calculations to quantify the electrical quantum transport properties of single molecules and small clusters. This approach allows for simultaneous measurement of the SAM's nanomechanical properties, as well as electrical and/or thermoelectric response, enabling correlation of film properties.
Article
Nanoscience & Nanotechnology
Ruth Sang Jones, Sergio Gonzalez-Munoz, Ian Griffiths, Philip Holdway, Koen Evers, Santamon Luanwuthi, Barbara M. Maciejewska, Oleg Kolosov, Nicole Grobert
Summary: This study reports the synthesis of macroscopic sheet assemblies called buckypapers composed of carbon/boron nitride core-shell heteronanotubes (MWCNT@BNNT) or boron nitride nanotubes (BNNTs). The MWCNT@BNNTs were synthesized using Atmospheric Pressure Chemical Vapor Deposition (APCVD) and a safe h-BN precursor ammonia borane. These buckypapers showed improved thermal conductivity compared to control samples, as measured using a novel technique called piercing SThM (pSThM). The results of this work provide valuable insights into the thermal properties of MWCNT@BNNT buckypapers and BNNT buckypapers synthesized by low-energy techniques.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Yi Li, Yasmin Teixeira, Gina Parlato, Jaclyn Grace, Fei Wang, Bryan D. Huey, Xueju Wang
Summary: This study presents a facile and versatile strategy to achieve reversible shape-morphing and color-changing capabilities in functional structures using liquid crystal elastomer (LCE) structures incorporated with thermochromic dyes. By controlling the transition temperature of the LCEs and the critical color-changing temperature of the dyes, the 3D thermochromic LCE structures can change their shapes and colors simultaneously. Demonstrations, including simulated blooming process, camouflage behavior, and underwater camouflage, highlight the reliability of this strategy. Furthermore, integration of micro-ferromagnetic particles allows the octopus thermochromic LCE robot to respond to thermal-magnetic dual stimuli for adaptive motion and diverse biomimetic motion modes, accompanied by color-changing behaviors.
Article
Chemistry, Multidisciplinary
Mangayarkarasi Nagarathinam, Cindy Soares, Yue Chen, Valerie R. Seymour, Vlastimil Mazanek, Mark A. Isaacs, Zdenek Sofer, Oleg Kolosov, John M. Griffin, Nuria Tapia-Ruiz
Summary: This study presents a comprehensive investigation on the use of ammonium vanadate (Vo2) as a cathode material in AZIBs, which has not been explored before.