4.5 Article

Multidimensional SPM applied for nanoscale conductance mapping

Journal

JOURNAL OF MATERIALS RESEARCH
Volume 28, Issue 24, Pages 3311-3321

Publisher

CAMBRIDGE UNIV PRESS
DOI: 10.1557/jmr.2013.365

Keywords

-

Funding

  1. Velux Foundation
  2. iNANO
  3. NSF:DMR:Ceramics [0909091]
  4. NSF:DMR:IMR [0817263]
  5. EPSRC-NSF [EP/G06556X/1]
  6. EU [FUNPROB]
  7. Division Of Materials Research
  8. Direct For Mathematical & Physical Scien [0909091, 0817263] Funding Source: National Science Foundation
  9. EPSRC [EP/G06556X/1, EP/K023373/1] Funding Source: UKRI
  10. Engineering and Physical Sciences Research Council [EP/G06556X/1, EP/K023373/1] Funding Source: researchfish

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A new approach has been developed for nanoscale conductance mapping (NCM) based on multidimensional atomic force microscopy (AFM) to efficiently investigate the nanoscale electronic properties of heterogeneous surfaces. The technique uses a sequence of conductive AFM images, all acquired in a single area but each with incrementally higher applied voltages. This generates a matrix of current versus voltage (I-V) spectra, providing nanoscale maps of conductance and current nonlinearities with negligible spatial drift. For crystalline and amorphous phases of a GeSe chalcogenide phase change film, conductance and characteristic amorphous phase turn-on voltages are mapped with results providing traditional point-by-point I-V measurements, but acquired hundreds of times faster. Although similar to current imaging tunneling spectroscopy in a scanning tunneling microscope, the NCM technique does not require conducting specimens. It is therefore a promising approach for efficient, quantitative electronic investigations of heterogeneous materials used in sensors, resistive memories, and photovoltaics.

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