4.5 Article

Direct formation of nanostructured graphitic carbon from an acrylic ion-exchange resin at 600°C

Journal

JOURNAL OF MATERIALS RESEARCH
Volume 26, Issue 24, Pages 3083-3090

Publisher

CAMBRIDGE UNIV PRESS
DOI: 10.1557/jmr.2011.395

Keywords

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Funding

  1. National Natural Science Foundation of China [21073241, U1034003, 21106190]
  2. China National 863 Program [2009AA034400]
  3. Sun Yat-sen University [30000-3126170]
  4. Ministry of Education of China [20100171120022]
  5. Yat-sen Innovative Talents Cultivation Program for Excellent Tutors

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Graphitic carbon (GC) is prepared using an ion-exchange resin as carbon source at 600 degrees C. A Co salt is selected as the graphitization catalyst and is pre-exchanged onto the resin during the ion-exchange process. The GC is characterized by transmission electron microscopy, x-ray diffraction, Raman spectroscopy, and thermogravimetry. Analysis of the crystallization shows that graphitization can occur at a temperature of as low as 600 degrees C, compared to the usual temperature of above 2000 degrees C in industry and above 1000 degrees C in literature. Different carbon structures have been found for different pretreatments of the resin and different heat treatment temperatures. This energy-saving method is an important breakthrough for the economic mass production of GC.

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