4.5 Article

Tarnishing film-induced brittle cracking of brass

Journal

JOURNAL OF MATERIALS RESEARCH
Volume 24, Issue 7, Pages 2409-2415

Publisher

CAMBRIDGE UNIV PRESS
DOI: 10.1557/JMR.2009.0289

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Funding

  1. National Natural Science Foundation of China [50671007, 50731003]
  2. National Key Technology RD Program [2007BAB27B05]

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Tarnishing film was developed on the brass surface in Mattsson's solution at room temperature. The filmed brass was removed from the solution, dried, and subjected to a slow strain rate (loading speed = 0.5 mm/min) in air for studying the effect of the film on crack propagation in the brass substrate. It was observed that initial cracks started to emerge in the film and then propagated to the brass matrix in a brittle intergranular manner. However, it changed into a ductile mode after removing the deposited film. The galvanic current between platinum wire and filmed brass sample in Mattson's solution was investigated. The results showed that periodic current fluctuations were observed when the sample was under a constant applied load. These observations showed that the film rupture-formation occurred at cracks under the stress-corrosion cracking condition.

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