Article
Chemistry, Physical
Jing Zhang, Weiqi Liao, Hao Zheng, Yunshang Zhang, Lebing Xia, Bo-Tao Teng, Ji-Qing Lu, Weixin Huang, Zhenhua Zhang
Summary: The effects of Pd catalysts supported on different exposed facets of anatase TiO2 nanocrystals on the hydrogenation of CO2 to formate were investigated. It was found that the 2%Pd/TiO2 {1 0 0} catalyst exhibited high activity and stability, with a high turnover frequency and stability. This can be attributed to the higher density of moderate basic sites and higher oxygen vacancy concentration on the TiO2 {1 0 0} surface, which promote the activation of CO2 and H-2, and the formation of stable Pd particles.
JOURNAL OF CATALYSIS
(2022)
Article
Chemistry, Physical
Xu Fang, Aixin Fan, Zhen Wang, Yao Wang, Yunrui Li, Shuna Li, Yinghao Wang, Chenglong Dong, Haixiao Sun, Yuanyuan Liu, Xin Zhang, Yehua Han, Xiaoping Dai
Summary: Efficient nanostructured catalysts Pt-FeNi @ C, Pt-Fe @ C, and Pt-Ni @ C were developed for the selective hydrogenation of 4-carboxybenzaldehyde (4-CBA), achieving excellent 4-hydroxymethylbenzoic acid (4-HMBA) and benzoic acid (BA) selectivity. Among them, Pt-FeNi @ C catalyst showed outstanding recyclability and catalytic activity.
JOURNAL OF CATALYSIS
(2021)
Article
Chemistry, Applied
Chenggong Yang, Donge Wang, Rong Huang, Jianqiang Han, Na Ta, Huaijun Ma, Wei Qu, Zhendong Pan, Congxin Wang, Zhijian Tian
Summary: MoS2-TiO2 nanocomposite catalysts with Janus structure were synthesized via a simple solvothermal method. The nanocomposite catalysts exhibited strong interaction between MoS2 layers and TiO2 nanoparticles, resulting in enhanced catalytic activity and stability for phenanthrene hydrogenation.
CHINESE JOURNAL OF CATALYSIS
(2023)
Article
Engineering, Environmental
Jiaxiang Zhang, Tianzuo Wang, Chengxiang Shi, Lun Pan, Xiangwen Zhang, Chong Peng, Ji-Jun Zou
Summary: An ammonium citrate assisted impregnation method was developed to fabricate loaded Ni catalyst for hydrogenation. The catalyst exhibits superior activity and high stability, making it suitable for hydrogenation of olefins and aromatics under low temperature conditions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Fufeng Cai, Yanjiao Guo, Jessica Juweriah Ibrahim, Jun Zhang, Yuhan Sun
Summary: A series of Pd/MoC catalysts were prepared and evaluated for hydrogen production from methanol decomposition, with 0.5Pd/MoC catalyst showing superior catalytic efficiency and stability compared to traditional CuZnAl catalyst. Strong interaction between Pd particles and alpha-MoC1-x phase on the 0.5Pd/MoC catalyst contributed to its stable catalytic performance.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Multidisciplinary
Sho Yamaguchi, Shu Fujita, Kiyotaka Nakajima, Seiji Yamazoe, Jun Yamasaki, Tomoo Mizugaki, Takato Mitsudome
Summary: The study presents a non-noble metal catalyst, nickel phosphide nanoparticle supported on hydrotalcite, which effectively catalyzes the selective hydrogenation of d-glucose to d-sorbitol in water, with high yield and over 99% selectivity under mild conditions. This nano-Ni2P/HT catalyst shows superior activity compared to other non-noble metal catalysts, can operate at ambient temperature under just 1 bar of H-2, and is stable and reusable, providing a cheap, green, and sustainable route for the production of d-sorbitol.
Article
Biochemistry & Molecular Biology
Xingli Zheng, Yan Li, Wendian Li, Xianglin Pei, Dongdong Ye
Summary: Researchers used renewable resource chitosan (CS) derived from seafood wastes as carriers to design two different chitosan-supported palladium (Pd) nano-catalysts through different activation methods. The Pd particles were evenly and firmly dispersed on the chitosan microspheres due to the porous structure and functional groups of chitosan, as confirmed by various characterizations. The chitosan supported catalysts (Pd@CS) showed competitive catalytic activity in the hydrogenation of 4-nitrophenol and exhibited excellent catalytic activity, reusability, long-life, and broad applicability in selective hydrogenation of aromatic aldehydes, suggesting potential for green industrial catalysis applications.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Energy & Fuels
Zhou Yang, Shunqin Liang, Limin Sun, Xiaoli Hu, Weiping Fang, Weikun Lai, Xiaodong Yi
Summary: By constructing a hierarchical Pd/MgAl2O4@MgO catalyst, electronic metal-support interaction was achieved to enhance catalytic performance. The catalyst exhibited superior activity and stability in the selective hydrogenation of isoprene.
Article
Engineering, Chemical
Zhisheng Shi, Qingqing Tan, Dongfang Wu
Summary: The study demonstrates that mixed-phase indium oxide shows significantly improved catalytic hydrogenation of CO2 to CH3OH compared to single-phase indium oxide. The mixed-phase catalyst exhibits better CO2 conversion and CH3OH space-time yield, with a significant enhancement in catalytic performance attributed to the mixed-crystal effect resulting from phase mixing. The stable nature and difficulty of reduction of the mixed-phase catalyst during reaction indicate its potential as a highly active and long-lived CO2 hydrogenation catalyst.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Energy & Fuels
Hua Yan, Xiaowei Liu, Junhong Zhou, Dawei Li, Xiaoye Yang, Yiming Gu, Hongjiu Su, Shudong Wang
Summary: In this study, a amine-modified catalyst, Pd/A/SiO2, was designed and synthesized for anthraquinone (AQ) hydrogenation. Multiple techniques were used to characterize the catalysts' structural and electronic properties. The results showed that Pd/A/SiO2 exhibited superior performance and selectivity in AQ hydrogenation, providing insights for the development of highly efficient catalysts.
Article
Chemistry, Physical
Xuejie Zhang, Yebin Zhou, Guowei Li, Lei Zhang, Chunyu Yin, Yuanyuan Yang, Hongzheng Wang, Feng Feng, Linwei Wei, Qunfeng Zhang, Feng Yang, Lili Lin, Chunshan Lu, Xiaonian Li
Summary: Developing sulfur resistant and stable hydrogenation catalysts with high activity is important for the production of value-added chemicals, as it allows for the use of crude raw materials, reduces environmental impact, and saves energy.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Environmental Sciences
Le Yu, Di Li, Zhaoyi Xu, Shourong Zheng
Summary: Liquid phase catalytic hydrogenation reduction is a feasible method to eliminate Cr(VI) in water. Carbon nanotube supported Pt catalyst coated by polyaniline was prepared and applied in this study. Despite being completely wrapped by PANI layers, Pt/CNT@PANI remains highly active for Cr(VI) reduction and shows high catalyst stability after multiple cycles.
Article
Chemistry, Physical
Xiaogang Liu, Wenjie Chen, Wei Wang
Summary: Catalysts of Fe2O3/Pd with varying Pd loadings were prepared using impregnation and coprecipitation methods, and their catalytic hydrogen production performance was systematically studied under different conditions. Through optimizing the Pd loadings, formaldehyde concentration, sodium hydroxide concentration, and reaction temperature, a hydrogen production rate of 293.98 mL min(-1) g(-1) over Fe2O3/Pd with a Pd loading of 1 wt% at 298 K was achieved.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Zhuo Ma, Lei Ma, Xingkun Chen, Xuepeng Wang, Yuan Tan, Wenshao Yang, Shuang Wang, Li Yan, Kaixin Zhu, Yunjie Ding
Summary: In the hydrogenation of 3-hydroxypropionitrile, the Ni-Re/SiO2 catalyst achieved a high selectivity of over 96% and a conversion rate of 100%, along with outstanding long-term stability. This can be attributed to the contributive role of Re in facilitating hydrogen dissociation and intermediates adsorption.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Chenggen Li, Qingyang Zhang, Zhenggang Xu, Li Liu, Ting Zhu, Zhiwen Chen, Yuan Dong, Ming Yang
Summary: In this work, a highly dispersed CeO2 nanoparticle-modified Pd/Al2O3 catalyst was prepared and applied for the reversible hydrogenation and dehydrogenation of N-propylcarbazole. The catalyst Pd/CeAl-20 exhibited better catalytic performance compared to the commercially available 1 wt% Pd/Al2O3 catalyst, achieving complete hydrogenation and dehydrogenation within 180 minutes. This study reveals the crucial role of combined promotion of the active site size and chemical microenvironment for N-heterocycle hydrogenation and dehydrogenation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Zhong-Shuai Wu, Yijun Zheng, Shuanghao Zheng, Sen Wang, Chenglin Sun, Khaled Parvez, Taichi Ikeda, Xinhe Bao, Klaus Muellen, Xinliang Feng
ADVANCED MATERIALS
(2017)
Article
Chemistry, Applied
Li Xu, Chuan Shi, Bingbing Chen, Qi Zhao, Yongjun Zhu, Hermann Gies, Feng-Shou Xiao, Dirk De Vos, Toshiyuki Yokoi, Xinhe Bao, Ute Kolb, Mathias Feyen, Stefan Maurer, Ahmad Moini, Ulrich Mueller, Weiping Zhang
MICROPOROUS AND MESOPOROUS MATERIALS
(2016)
Article
Chemistry, Physical
Hengchang Liu, Yuanhu Zhu, Qinglong Meng, Xiaowei Lu, Shuang Kong, Zhiwei Huang, Peng Jiang, Xinhe Bao
Article
Multidisciplinary Sciences
Yang Yang, Qiang Fu, Wei Wei, Xinhe Bao
Article
Chemistry, Physical
Yuanli Hu, Xiulian Pan, Xiuwen Han, Xinhe Bao
JOURNAL OF PHYSICAL CHEMISTRY C
(2017)
Correction
Chemistry, Multidisciplinary
Fan Cai, Dunfeng Gao, Hu Zhou, Guoxiong Wang, Ting He, Huimin Gong, Shu Miao, Fan Yang, Jianguo Wang, Xinhe Bao
Article
Chemistry, Multidisciplinary
Jianping Xiao, Xiulian Pan, Fan Zhang, Haobo Li, Xinhe Bao
Article
Chemistry, Multidisciplinary
Fan Cai, Dunfeng Gao, Hu Zhou, Guoxiong Wang, Ting He, Huimin Gong, Shu Miao, Fan Yang, Jianguo Wang, Xinhe Bao
Article
Multidisciplinary Sciences
Guofeng Zhao, Fan Yang, Zongjia Chen, Qingfei Liu, Yongjun Ji, Yi Zhang, Zhiqiang Niu, Junjie Mao, Xinhe Bao, Peijun Hu, Yadong Li
NATURE COMMUNICATIONS
(2017)
Article
Multidisciplinary Sciences
Yun Liu, Fan Yang, Yi Zhang, Jianping Xiao, Liang Yu, Qingfei Liu, Yanxiao Ning, Zhiwen Zhou, Hao Chen, Wugen Huang, Ping Liu, Xinhe Bao
NATURE COMMUNICATIONS
(2017)
Article
Chemistry, Physical
Shuang Kong, Tianmin Wu, Min Yuan, Zhiwei Huang, Qing-Long Meng, Qike Jiang, Wei Zhuang, Peng Jiang, Xinhe Bao
JOURNAL OF MATERIALS CHEMISTRY A
(2017)
Article
Chemistry, Physical
Xiaoqi Chen, Liang Yu, Suheng Wang, Dehui Deng, Xinhe Bao
Review
Chemistry, Multidisciplinary
Qiang Fu, Xinhe Bao
CHEMICAL SOCIETY REVIEWS
(2017)
Article
Electrochemistry
Fan Cai, Dunfeng Gao, Rui Si, Yifan Ye, Ting He, Shu Miao, Guoxiong Wang, Xinhe Bao
ELECTROCHEMISTRY COMMUNICATIONS
(2017)
Article
Chemistry, Multidisciplinary
Shuanghao Zheng, Xingyan Tang, Zhong-Shuai Wu, Yuan-Zhi Tan, Sen Wang, Chenglin Sun, Hui-Ming Cheng, Xinhe Bao