Article
Chemistry, Applied
Wenyan Wu, Yihuan Wang, Zhijie Zhang, Fang Wang, Sheng Lu, Xiaoqiang Chen
Summary: The thermochromic properties of PDA/PEO composite films were investigated to understand their energy landscapes and proposed potential mechanisms for the generation of multiple energy minima based on the chemical structures of PDA head groups. Delicate devices for secret codes with multiple deciphering pathways and temperature sensors with a high-temperature recording function were fabricated utilizing the finely tuned chromic responsiveness of the composite films under thermo-and pH stimulations.
Article
Chemistry, Physical
A. S. El-Tabei, M. A. Hegazy, A. H. Bedair, N. M. El Basiony, M. A. Sadeq
Summary: Two compounds were synthesized via Mannich reaction and novel cationic surfactants were obtained. The study found that one of the surfactants showed better performance in corrosion inhibition and antimicrobial activity, providing effective protection for steel surfaces.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Mudussar Ali, Muhammad Usman, Afzal Shah, Abdul Rehman
Summary: Organic dyes, particularly those with hydrophobic properties, face solubility challenges in water-based applications. This study explores the use of various anionic and cationic surfactants to enhance the solubility and stability of a cationic dye, with spectrophotometric data providing insights into partition coefficients and binding constants. Additionally, the study examines the differences between mixed micellar media and solo surfactant systems in terms of binding and partitioning abilities, highlighting the synergistic effects between cationic and anionic components.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Multidisciplinary
Alpna Bisht, Matias Zuniga-Bustos, Garima Prasher, Surbhi Gautam, Horacio Poblete, Raman Preet Singh
Summary: Polyoxyethylene sorbitan monooleate is commonly used to stabilize dispersion of carbon nanoparticles such as carbon nanotubes and graphene. However, the mechanism of dispersion is not well understood. This study used spectroscopy and molecular dynamics simulations to investigate the mechanism of stabilization of carbon nanoparticles by Tween-80. The results showed that Tween-80 adsorbs onto the surface of carbon nanotubes and graphene through interaction between the alkyl chain and the aromatic rings, and the hydrophilic chains stabilize the suspension by steric hindrance. The simulations also revealed concentration-dependent changes in the nature of interactions between Tween-80 and the carbon nanoparticles, with aggregation shifting from planar to micelle-like structures.
Article
Chemistry, Multidisciplinary
Yutan Shen, Shikun Li, Ruilian Qi, Chunxian Wu, Ming Yang, Jie Wang, Zhuojun Cai, Kaiang Liu, Jiling Yue, Bo Guan, Yuchun Han, Shu Wang, Yilin Wang
Summary: HCISs are fabricated by non-covalent assembly of plant gallic acid with quaternary ammonium surfactants, providing long-lasting antimicrobial performance with multistage release of antimicrobial ingredients. They exhibit broad-spectrum antimicrobial activity against bacteria and fungi, and have good biocompatibility with mammalian cells. This low-cost and portable antimicrobial agent meets the growing demand for infection control in public spaces.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Zheng Yue, Meihuan Yao, Guangyue Bai, Jiuxia Wang, Kelei Zhuo, Jianji Wang, Yujie Wang
Summary: This study investigated the impact of cationic gemini surfactants on the enzymatic activity and conformation of alpha-chymotrypsin (α-CT), finding that the surfactants led to superactivity of α-CT below the critical micelle concentration, and the charge density of headgroups was regulated through electrostatic interactions. Characterization using isothermal titration calorimetry (ITC) revealed an endothermic enthalpy change, indicating a change in conformation and enzymatic superactivity. Fluorescence spectroscopy, circular dichroism (CD), and differential scanning calorimetry (DSC) demonstrated that the gemini surfactants induced and regulated different protein structures. The findings are significant for understanding the activation and denaturation mechanisms of enzymes.
Article
Biotechnology & Applied Microbiology
E. Paluch, J. Szperlik, T. Czuj, M. Cal, L. Lamch, K. A. Wilk, E. Oblak
Summary: The research found that the mechanism of perforation of cell membranes commonly associated with surfactants does not apply to cationic dicephalic surfactants, which instead act by increasing cell membrane permeability, leading to lipid droplet aggregation and morphological changes in fungal cells. Additionally, these compounds induce oxidative stress within cells, including increased production of superoxide anion radicals and mitochondrial oxidative stress.
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Petra Holinkova, Filip Mravec, Tereza Venerova, Chien-Hsiang Chang, Miloslav Pekar
Summary: This study investigated the interactions between hyaluronan and micelles formed by cationic surfactants using fluorescence resonance energy transfer (FRET). The results showed that the addition of hyaluronan led to the formation of a pearl necklace structure with smaller micelles compared to pure surfactant. This research is of significance for the formulation of drug delivery systems.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Thermodynamics
Bruna Michele Arruda de Brito Buriti, Maria Eduarda Barsosa, Josue da Silva Buriti, Juliana de Melo Cartaxo, Heber Sivini Ferreira, Gelmires de Araujo Neves
Summary: This study aimed to synthesize and characterize organically modified palygorskite clay using cationic and nonionic surfactants for potential usage in oil-based drilling fluids. The results showed that the organophilization process was effective, and the modified clay displayed good rheological properties and thermal stability at high temperatures, making it suitable as an additive in oil-based drilling fluids.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Article
Chemistry, Physical
Jinglin Tan, Yue-Fei Zhang
Summary: Cationic trisiloxane surfactants based on PEG were synthesized and their micellization behavior in aqueous solution was studied. The introduction of ethylene glycol segments resulted in lower CMC values and larger surface tension compared to permethyltrisiloxane surfactants, forming spherical aggregates driven by enthalpy.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Analytical
V. G. Amelin, Z. A. Ch. Shogah, D. S. Bol'shakov
Summary: A method for determining cationic and anionic surfactants in food products using dispersive liquid-liquid microextraction and smartphone-based colorimetric measurements of fluorescence parameters is proposed. The method allows for the detection of different types of surfactants in various food products with detection and quantification limits in the ranges 0.005-0.05 and 0.01-0.1 mg/L, respectively. The duration of analysis is relatively short at 20-30 minutes with good reproducibility.
JOURNAL OF ANALYTICAL CHEMISTRY
(2021)
Editorial Material
Chemistry, Multidisciplinary
Yuki Mochizuki, Hiroaki Imai, Yuya Oaki
Summary: This study demonstrates the interlayer interaction between host and guest in organic layered materials through hydrogen bonding, facilitating thermoresponsive color changes over a wide temperature range.
Article
Chemistry, Multidisciplinary
Mingzhu Liu, Jiemin Fu, Shu Yang
Summary: This study reports on the synthesis of liquid crystalline elastomer (LCE) microparticles with temperature-dependent anisotropic shapes, which can change their shapes in response to external stimuli. The Janus microdroplets, consisting of a mixture of liquid crystal monomers, oligomers, silicone oil, and an organic solvent, are transformed into LCE microparticles with diverse shapes after polymerization and solvent extraction. The choice of surfactants, concentration, and composition, as well as the weight ratio of the components, plays a crucial role in determining the final shape of the microparticles.
Article
Spectroscopy
Changsheng Gan, Rong Cheng, Kunliang Cai, Xiaonan Wang, Chenkun Xie, Tiantian Xu, Chuanxun Yuan
Summary: The interactions between calf thymus DNA and a series of glucose-based cationic gemini surfactants with different spacer length were studied. The results showed that all the surfactants could efficiently interact with DNA, causing changes in its absorption intensity and conformation. Surfactant 1c exhibited the most significant effect, compacting the DNA molecules to a smaller size. These findings shed light on the potential applications of cationic gemini surfactants in gene delivery.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Physical
A. Elaraby, Amr Elgendy, M. Abd-El-Raouf, M. A. Migahed, A. S. El-Tabei, Aboubakr M. Abdullah, Noora H. Al-Qahtani, Sami M. Alharbi, Samy M. Shaban, Dong-Hwan Kim, N. M. El Basiony
Summary: In this study, effective Gemini cationic surfactants (CSII, CSIV) were synthesized and characterized. The adsorptive properties of CSII and CSIV at HCl/air and C-steel/HCl interfaces were investigated using surface tension and electrochemical parameters. The results showed that CSII and CSIV have high adsorption affinity at the HCl/air interface, with aliphatic chains promoting surfactant adsorption. Electrochemical impedance spectroscopy and potentiodynamic polarization revealed that CSII and CSIV act as mixed inhibitors, significantly enhancing the charge transfer resistance of C-steel in HCl. Theoretical calculations and simulations supported the experimental findings, demonstrating the relationship between corrosion inhibition and molecular structure.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Biochemistry & Molecular Biology
Sompriya Chatterjee, Abbas Salimi, Jin Yong Lee
Summary: This study investigated the impact of a Pro525Arg mutation in the FUS protein on stability and function, revealing that the mutation results in a less stable and more compact protein structure. Furthermore, the mutation alters the nuclear function of FUS, potentially leading to its accumulation in the cytoplasm.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2021)
Article
Chemistry, Physical
Yuan Yuan, Jiapeng Ma, Si Wu, Jin Yong Lee, Baotao Kang
Summary: A novel all-carbon material, supertetrahedraphene, was proposed and investigated with the insertion of acetylenic linkage to change its properties, suggesting a strategy to design carbon materials with desired properties.
Article
Biochemistry & Molecular Biology
Abbas Salimi, Hao Li, Jin Yong Lee
Summary: The study indicates that the tautomeric effect of histidine and (epsilon delta delta) homodimers play a crucial role in the early stage of A beta aggregation, potentially leading to more beta-sheet formation.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Chemistry, Physical
Yuan Yuan, Jiapeng Ma, Hongqi Ai, Baotao Kang, Jin Yong Lee
Summary: Through density functional theory calculations, this study identified graphyne nanotubes as potential metal-free electrocatalysts with superior hydrogen evolution and oxygen reduction reaction activity compared to platinum. Additionally, a linear relationship between O2 adsorption Gibbs free energy change and H adsorption binding energy was revealed, suggesting a potential general descriptor for the rational design of bifunctional graphyne materials. This research provides a simple strategy for the rational design of bifunctional materials.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Biochemistry & Molecular Biology
Hao Li, Eunjung Joo, Jin Yong Lee
Summary: Research suggests that the P332L mutation and histidine tautomerism affect the stability of tau protein structures, leading to a higher aggregation tendency.
ACS CHEMICAL NEUROSCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Hong-Bo Cheng, Hao Dai, Xiaoqiong Tan, Hao Li, Huihui Liang, Chenyan Hu, Mingwei Huang, Jin Yong Lee, Jing Zhao, Liming Zhou, Yuguang Wang, Liqun Zhang, Juyoung Yoon
Summary: This article introduces a novel supramolecular theranostic system that combines biomarker protein activation and a host-guest strategy. The authors demonstrate the design of a nanoparticulate theranostic agent that can detect albumin and treat cancer. The system also exhibits enhanced biocompatibility and photothermal conversion efficiency, making it a promising strategy for photodynamic and photothermal immunotherapy.
ADVANCED MATERIALS
(2022)
Article
Engineering, Environmental
Yipin Lv, Baotao Kang, Yuan Yuan, Guozhu Chen, Jin Yong Lee
Summary: This study demonstrates that gamma GyNRs can serve as excellent bifunctional electrocatalysts after functionalization, with the binding strength of H atom acting as a general descriptor for designing bifunctional electrocatalysts. By incorporating scaling relationship analysis and a machine learning algorithm, deeper insights into the reaction mechanisms were gained, providing valuable information for the rational design of novel CMFCs.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Baotao Kang, Yuan Yuan, Yipin Lv, Hongqi Ai, Jin Yong Lee
Summary: This study focuses on developing efficient and low-cost electrocatalysts for the nitrogen reduction reaction (NRR) under ambient conditions. By doping gamma-graphyne with B, N, O, P, and S, the researchers identified a specific configuration that exhibited excellent NRR activity. The findings provide insight into improving NRR activity and offer a new strategy for developing metal-free catalysts for this reaction.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Biochemistry & Molecular Biology
Abbas Salimi, Sompriya Chatterjee, Jin Yong Lee
Summary: Clinical research suggests that Type 2 diabetes (T2D) may be a risk factor for Alzheimer's disease (AD) development, possibly due to the improper aggregation of Amyloid-beta (Aβ) in both diseases. This computational research reveals the cross-seeding between Amylin1-37 and Aβ 40, shedding light on the pathological link between AD and T2D.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Physical
Yeonsig Nam, Daniel Keefer, Artur Nenov, Irene Conti, Flavia Aleotti, Francesco Segatta, Jin Yong Lee, Marco Garavelli, Shaul Mukamel
Summary: The study compares the probing of the S-2 -> S-1 Coin passage in 4-thiouracil using TrueCARS and TRXD spectroscopy. Quantum nuclear wavepacket dynamics provides an accurate picture of the photoinduced dynamics. The two signals, TrueCARS spectrogram and TRXD signal, offer a complementary picture of the nonadiabatic passage for studying the underlying photophysics in thiobases.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Analytical
Qian Cheng, Jinhui Feng, Tingting Wu, Yujian Guo, Xu Sun, Xiang Ren, Jin Yong Lee, Lei Liu, Qin Wei
Summary: A novel signal-off type photoelectrochemical (PEC) immunosensor was developed using Bi2S3/I:BiOCl and Au NPs@CoSnO3 as materials for sensitive detection of CYFRA 21-1. The heterostructure was formed through a simple, fast, low temperature production process with no complex raw materials, achieving a low detection limit and displaying good specificity and stability.
Article
Chemistry, Physical
Jinze Li, Hao Li, Wenfu Xie, Shijin Li, Yuke Song, Kui Fan, Jin Yong Lee, Mingfei Shao
Summary: The study introduced a fast and simple flame-assisted strategy to construct oxygen-coordinated single-atom catalysts on integrated carbon nanotube arrays, showing promising performance in electrocatalysis. Through density functional theory calculations, it was demonstrated that oxygen in the carbon substrate provides homogeneous sites for efficient anchoring of metal atoms, resulting in optimized activities of the single-atom catalysts.
Article
Engineering, Multidisciplinary
Xiaotong Han, Nannan Li, Peixun Xiong, Yingbo Kang, Qingyun Dou, Qing Liu, Wenwu Li, Jin Yong Lee, Ho Seok Park
Summary: In this study, a free-standing trifunctional and durable electrocatalyst was developed, achieving high activities and efficiencies in water electrolysis and rechargeable Zn-air batteries.
COMPOSITES PART B-ENGINEERING
(2022)
Article
Chemistry, Physical
Yuan Yuan, Xiaoxue Song, Baotao Kang, Jin Yong Lee
Summary: This article reports a novel 2D carbon nitride, C6N3, and investigates its performance as a single-atom catalyst in the electrocatalytic hydrogen evolution reaction (HER). The study reveals that C6N3 with embedded certain transition metals exhibits excellent stability, binding strength, and electrical conductivity, demonstrating its great potential in HER. Further research is needed to explore the properties and applications of C6N3 in other fields.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Yuan Yuan, Xiaoxue Song, Jiapeng Ma, Yanqi Chen, Fangfang Wang, Baotao Kang, Jin Yong Lee
Summary: Sodium-ion batteries (SIBs) are considered as promising alternatives to lithium-ion batteries (LIBs) due to the abundance and lower cost of sodium. This study explores the potential of alpha, beta, and gamma graphyne nanotubes as SIB anodes using density functional theory calculations. The results show that alpha graphyne nanotubes have the highest sodium storage capacity among the three types, attributed to their largest specific surface area. Furthermore, the larger pores in alpha and beta graphyne nanotubes facilitate easier diffusion and penetration of sodium atoms, indicating better rate capacity.