Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 32, Pages 6780-6788Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm00421a
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Funding
- Ministerio de Educacion y Ciencia [CTQ2006-15456-C04-03/BQU, MAT2009-14564-C04-04]
- Generalitat Valenciana [GV2008/352, PROM-ETEO/2009/108]
- MEC from Spain for Ramon Cajal
- Juan de la Cierva
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The nanometric organization of MOx (M = Co, Zn, Ni) domains partially embedded inside the mesoporous silica walls but accessible to the pore voids, which is achieved through a simple one-pot surfactant-assisted procedure, define optimal anchors for the nucleation and growth of gold nanoparticles, which in turn favours an exceptional thermal stability for the final Au-supported materials. As silica support we have selected a UVM-7 silica having a highly accessible architecture defined by two hierarchic pore systems. The combination of nanometric pore length, tortuous mesopores and MOx inorganic anchors favours the stability of the final Au/CoOx-UVM-7 nanocomposites.
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