4.5 Article

Magnetic properties and 57Fe NMR studies of U-type hexaferrites

Journal

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Volume 323, Issue 16, Pages 2210-2213

Publisher

ELSEVIER
DOI: 10.1016/j.jmmm.2011.03.033

Keywords

U-type hexaferrrite; XRD; EDX; Fe-57; NMR; Magnetic hysteresis

Funding

  1. Estonian Science Foundation [MJD 65, ETF 6852, ETF 8440]
  2. [SF0690029s09]
  3. [SF0690034s09]

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U-type hexaferrites with compositions Ba4Me2Fe36O60 (Me=Cu, Fe, Co, Mn and Mg) have been synthesized and characterized by magnetization measurements and zero field Fe-57 nuclear magnetic resonance (NMR) spectra. The NMR spectra show resonance peaks corresponding to different crystallographic sites of iron (tetrahedral, octahedral and trigonal bipyramidal) with integral intensities according to their site multiplicity. In comparison with the NMR spectrum of M-type barium hexaferrite the intensities of some of the peaks arising due to iron sublattices (f(IV), a and b sites) are different, though there is no difference in peak positions indicating the same local hyperfine field strength at Fe nuclei. The maximum saturation magnetization at room temperature was found in Cu2U (70 emu/g) and Fe2U (67 emu/g). The Curie temperatures, saturation magnetizations and coercitivities for the U-type hexaferrites are given. (C) 2011 Elsevier B.V. All rights reserved.

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