4.5 Article

The influence of Nd-Co substitution on the magnetic properties of non-stoichiometric strontium hexaferrite nanoparticles

Journal

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Volume 321, Issue 14, Pages 2245-2250

Publisher

ELSEVIER
DOI: 10.1016/j.jmmm.2009.01.033

Keywords

Strontium hexaferrite; Nd-Co substitution; Magnetic properties; Non-stoichiometric hexaferrite

Funding

  1. Universidad de Buenos Aires [I-055]
  2. Universidad Nacional de Cordoba [69/08]
  3. Conicet [PIP 6452]

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Non-stoichiometric Nd-Co substituted hexaferrites of composition Sr1-xNdxFe12(1-x)CoxO19 (x = 0-0.4) were prepared by the self-propagating combustion method and subsequent heat treatments. Structural characterization of samples showed that the M-type hexagonal structure can be maintained for substitutions x < 0.4 without the segregation of secondary phases on samples calcined at 1100 degrees C. The crystallites sizes range between 50 and 70 nm. Mossbauer spectroscopy results indicate that the iron vacancies are not evenly distributed over the lattice and that Co/Fe substitution mainly takes place in site 4f2. Magnetic measurements reveal that values of saturation magnetization MS increased from 72 to 76 Am-2/kg (x = 0-0.2), while coercivity H-c increased from 26.40 to 58.70 A/m (x = 0-0.3). Nd-Co substitutions enhance magnetic properties in deficient iron Sr hexaferrites. (c) 2009 Elsevier B.V. All rights reserved.

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