4.1 Article

Increased Flame Retardant, Smoke Suppressant and Mechanical Properties of Semi-Rigid Polyvinyl Chloride (PVC) Treated with Zinc Hydroxystannate Coated Dendritic Fibrillar Calcium Carbonate

Journal

JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
Volume 53, Issue 3, Pages 541-554

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00222348.2013.852061

Keywords

PVC; coated; calcium carbonate; flame retardant; zinc hydroxystannate

Funding

  1. Natural Science Fund of China [21276059]
  2. Science and Technology Project of Hebei Province [13211402D]
  3. Intramural Youth Fund of Hebei University [3333112]

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Zinc hydroxystannate (ZHS) coated dendritic fibrillar calcium carbonate (ZHSCC-(D)) and ZHS coated cubic calcium carbonate (ZHSCC(-C)) were prepared in the water solution of cetyl trimethyl ammonium bromide (CTAB)/glycerin and in a pure water solution, respectively. Compared with the semirigid polyvinyl chloride (PVC) treated with ZHSCC(-C), when the addition level and the effective flame retardant component of ZHS were the same, the semi-rigid PVC treated with ZHSCC(-D) showed a higher value of tensile strength, elongation and impact strength, and a lower smoke density rating (SDR) value than those of the semi-rigid PVC treated with ZHSCC(-C); except for the semi-rigid PVC treated with 10g ZHSCC(-C) (1:10) or ZHSCC(-D) (1:10) per 100g PVC, the semi-rigid PVC treated with ZHSCC(-D) had almost the same LOI value as that of the semi-rigid PVC treated with ZHSCC(-C). The semi-rigid PVC treated with 10g ZHSCC(-D) (1:10) per 100g PVC had the best integrated properties.

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