Journal
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
Volume 50, Issue 2, Pages 193-199Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/10601325.2013.742788
Keywords
Photo-responsive; Thermo-responsive; Self-assembled micelles; Azobenzene block polymer; PNIPAM
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Funding
- National Nature Science
- National Natural Science Foundation of China [50803044]
- Program of Innovative Research Team of Soochow University
- Qing Lan Project
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In this report, the photo and thermo dual responsive block copolymer, PVHMA-b-PNIPAM, is synthesized by reversible addition-fragmentation chain transfer polymerization. The structure of copolymer was characterized by GPC and NMR. The copolymer trends to form micelles in water. A photo controlled reversible size changing as well as temperature induced reversible precipitation and dispersion in water was found.
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