4.7 Article

Cavity-Enhanced IR Absorption in Planar Chalcogenide Glass Microdisk Resonators: Experiment and Analysis

Journal

JOURNAL OF LIGHTWAVE TECHNOLOGY
Volume 27, Issue 23, Pages 5240-5245

Publisher

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/JLT.2009.2030899

Keywords

Amorphous materials; chemical analysis; glass; IR spectroscopy; integrated optics; microresonators; optical resonators; sulfur compounds

Funding

  1. Department of Energy [DE-SC52-06NA27341]

Ask authors/readers for more resources

Planar microdisk optical resonators fabricated from Ge23Sb7S70 chalcogenide glass on a silicon substrate are applied for cavity-enhanced spectroscopic measurement of chemical molecular absorption fingerprint. A 0.02 cm(-1) detection limit for these devices is demonstrated. This detection limit represents a threefold improvement as compared to a straight waveguide sensor, while the physical device length is reduced by 40-fold. The reduction in device footprint with enhanced sensitivity makes the structure attractive for sensor-on-a-chip device applications. We also present a design optimization approach for cavity-enhanced IR absorption spectroscopy using traveling-wave resonators, which indicates that further performance improvement can be achieved in optimally coupled, low-loss resonant cavities.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Study of visible, NIR, and MIR spectroscopic properties of Er3+-doped tellurite glasses and glass-ceramics

Arnaud Lemiere, Bartosz Bondzior, Iisa Aromaki, Laeticia Petit

Summary: This paper reports on the structural, thermal, optical, and spectroscopic properties of Er3+-doped tellurite glasses with different compositions. It is found that the crystalline structures formed after thermal treatment significantly affect the intensity of upconversion and mid-infrared emissions from Er3+ ions.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Materials Science, Multidisciplinary

Demonstration of the hierarchical arrangement of persistent luminescent microparticles in direct doping-prepared photonic glasses using second-harmonic generation microscopy

Shambhavee Annurakshita, Vilma Lahti, Laeticia Petit, Godofredo Bautista

Summary: Using 3D second-harmonic generation microscopy, the formation and distribution of persistent luminescent microparticles in glasses prepared using the direct doping method are investigated. The microparticles show distinctive and highly localized patterns, with different characteristics depending on the doping temperature and dwell time.

OPTICAL MATERIALS EXPRESS (2022)

Article Materials Science, Multidisciplinary

Bioactive phosphate glass-based fiber with green persistent luminescence

A. Lemiere, A. Szczodra, S. Vuori, B. Bondzior, T. W. Hawkins, J. Ballato, M. Lastusaari, J. Massera, L. Petit

Summary: The first biophotonic composite fiber with green persistent luminescence was successfully prepared using commercial persistent luminescent microparticles and bioactive glass. The fibers exhibited green afterglow and maintained their bioactive response.

MATERIALS RESEARCH BULLETIN (2022)

Article Materials Science, Multidisciplinary

Investigations of the thermal, structural, and Near-IR emission properties of Ag containing fluorophosphate glasses and their crystallization process

Marwa Ennouri, Laeticia Petit, Habib Elhouichet

Summary: This work investigates the impact of Ag2O on the thermal, structural, and Near-IR luminescence of Er3+ doped calcium-fluorophosphate glasses. The amount of silver oxide significantly affects the thermal stability and crystallization process of the glass. Thermal treatment induces the precipitation of Ag nanoparticles within the glass network, leading to an enhancement in the Er3+ IR emission.

OPTICAL MATERIALS (2022)

Article Materials Science, Multidisciplinary

Spectroscopic properties of Er3+doped germanate glasses before and after a heat treatment process

Arnaud Lemiere, Bartosz Bondzior, Luukas Kuusela, Alexander Veber, Laeticia Petit

Summary: This paper reports the structural, thermal, and optical properties of Er3+ doped germanate glasses with various compositions. The glasses exhibit low phonon energies and high glass transition temperatures. Raman spectra show different polymerization degrees of the glasses. The thermal treatment results in the precipitation of crystals, composition of which depends on the glass composition. Er-doped crystals are found to affect the spectroscopic properties, leading to an increase in upconversion and MIR emissions, particularly in glasses with Y2O3, ZnO, and TiO2.

OPTICAL MATERIALS EXPRESS (2023)

Article Materials Science, Multidisciplinary

Celebrating Optical Glass - the International Year of Glass (2022): feature issue introduction

John Ballato, Ulrich Fotheringham, Mathieu Hubert, Stefan Nolte, Laeticia Petit, Kathleen A. Richardson

Summary: This feature issue introduces the historical and recent advances in optical glass. In celebration of the International Year of Glass (IYOG) declared by the United Nations in 2022, this issue includes a collection of twenty-seven manuscripts that showcase the processing, characterization/metrology, and applications where glass has made significant contributions to our world.

OPTICAL MATERIALS EXPRESS (2022)

Article Chemistry, Physical

Near-infrared rechargeable glass-based composites for green persistent luminescence

N. Garcia Arango, S. Vuori, H. Byron, D. Van der Heggen, P. F. Smet, M. Lastusaari, L. Petit

Summary: This study demonstrates the fabrication process of Yb3+, Tm3+ co-doped oxyfluorophosphate glass-based composites that exhibit green persistent luminescence when charged with near-infrared light. The mechanism behind the green afterglow and the optimization of up-conversion emission are investigated. The addition of SrAl2O4:Eu2+,Dy3+ crystals enhances the green afterglow effect.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Optics

The usability of the Judd-Ofelt theory for luminescent thermometry using Eu3+-doped phosphate glass

Bartosz Bondzior, Chi Nguyen, Thi Hong Quan Vu, Diego Pugliese, Przemyslaw J. Deren, Laeticia Petit

Summary: The Judd-Ofelt theory was tested on Eu3+-doped glasses to evaluate their potential as luminescent thermometers. The theory accurately estimated the thermometric sensitivity, and the addition of B2O3 or SiO2 increased the absolute sensitivity without affecting the position of Eu3+ ions.

JOURNAL OF LUMINESCENCE (2022)

Article Materials Science, Multidisciplinary

Impact of Al2O3, TiO2 and ZnO addition on the crystallization of Yb3+ doped phosphate glass-ceramic

Mikko Hongisto, Otto Linros, Sylvain Danto, Veronique Jubera, Laeticia Petit

Summary: The thermal and physical properties of Yb3+-doped phosphate glasses were studied. Changes in the glass composition impacted the glass structure and crystallization process, with the addition of Al2O3, TiO2, and ZnO promoting the formation of specific crystalline phases.

MATERIALS RESEARCH BULLETIN (2023)

Review Materials Science, Multidisciplinary

The past, present and future of photonic glasses: A review in homage to the United Nations International Year of glass 2022

Wilfried Blanc, Yong Gyu Choi, Xianghua Zhang, Marcelo Nalin, Kathleen A. Richardson, Giancarlo C. Righini, Maurizio Ferrari, Animesh Jha, Jonathan Massera, Shibin Jiang, John Ballato, Laeticia Petit

Summary: Since the 1960s, photonics has become an integral part of modern life, thanks to the invention and development of lasers. Glass, being versatile and easily fabricated, has played a crucial role in various applications related to the generation, transmission, modulation, amplification, conversion, and detection of light. This paper reviews the past, present, and future of photonic glasses in honor of the United Nations International Year of Glass 2022.

PROGRESS IN MATERIALS SCIENCE (2023)

Article Nanoscience & Nanotechnology

Unveiling the thermometric sensitivity of Eu3+doped glasses in various system from theory to experimental

Bartosz Bondzior, Thu Hoang, T. H. Quan Vu, Przemysaw J. Deren, Laeticia Petit

Summary: The thermometric sensitivity of different Eu3+ doped glasses in different glass systems was theoretically calculated using the Judd-Ofelt parameters and compared to experimental data. The study aimed to test the limitations of thermal sensitivity estimation using Judd-Ofelt parameters in various glass systems. Discrepancies between theoretical and experimental values were observed in germanate and tellurite glasses due to their low phonon energies, which caused the failure of the Boltzmann model. Phosphate glasses, with their high absolute thermometric sensitivity, are promising materials for luminescence thermometers.

SCRIPTA MATERIALIA (2023)

Article Materials Science, Ceramics

New Mg/Sr phosphate bioresorbable glass system with enhanced sintering properties

S. Ghanavati, L. Petit, J. Massera

Summary: Phosphate glasses are promising alternative materials to replace traditional silicate bioactive glasses due to their controlled ion release behavior. A newly developed bioresorbable phosphate glass containing Sr and Mg demonstrated slower dissolution rate and maintained their ability for congruent dissolution and hot forming. The substitution of SrO for MgO effectively enhanced the sintering ability of the material, enabling the processing of scaffolds with mechanical properties above that of cancellous bone.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2023)

Article Materials Science, Ceramics

Characterization of biodegradable core-clad borosilicate glass fibers with round and rectangular cross-section

Mikko Hongisto, Sonya Ghanavati, Arnaud Lemiere, Gregory Hauss, Shashank Boraiah, Louis Cornet, Angeline Poulon-Quintin, Dominique Pagnoux, Dominique Bernard, Jonathan Massera, Laeticia Petit, Veronique Jubera, Sylvain Danto

Summary: We have developed core-clad bioactive borosilicate fibers with round and rectangular cross-section profile by stacking and drawing glass slabs. Tens-of-meters-long fibers were successfully drawn, but rectangular ones suffered from elevated losses due to the enhanced corrosion caused by residual tensile stress. This study provides the first report on the effect of residual tensile stresses on the corrosion of rectangular fibers and highlights the importance of geometry in the biodegradation behavior of fiberglass.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Article Materials Science, Multidisciplinary

Fabrication and characterization of SiO2 glass containing YbPO4 crystals

Robert Mueller, Martin Lorenz, Alexander Veber, Roman Sajzew, Andre Kalide, Jens Kobelke, Anka Schwuchow, Luukas Kuusela, Lothar Wondraczek, Laetitia Petit, Katrin Wondraczek

Summary: In this study, silicate glass containing crystals were prepared by melting a mixture of YbPO4 xenotime structured crystals and SiO2 nanoparticles. The mixture was used to prepare large volume core preforms for laser active optical fiber. The integrity of the crystals in the preform and fiber were assessed through temperature dependent sintering and fiber drawing experiments. The survival of YbPO4 crystalline particles in silica was investigated using various techniques, showing that the particles withstand the high-temperature steps during the fiber fabrication process. However, partial decomposition of the crystals was observed during the fiber fabrication.

OPTICAL MATERIALS EXPRESS (2023)

Article Materials Science, Multidisciplinary

Monitoring decomposition of Eu3+doped LaPO4 nanocrystals in glass using Eu3+as an optical probe for applications in temperature sensing

Bartosz Bondzior, Chi Nguyen, T. H. Quan Vu, Przemyslaw J. Deren, Laeticia Petit

Summary: The method of directly introducing crystals of known chemistry, size, and optical properties into a glass matrix is useful in overcoming limitations in controlling crystal growth in glass-ceramics. By measuring changes in micro-luminescence spectra, it is possible to track the decomposition of crystals inside the composite material. It has been shown, for the first time, that adding Eu3+-doped LaPO4 crystals to phosphate fluoride glasses enhances the thermometric sensitivity of Eu3+ ions, making it promising for temperature sensing applications.

MATERIALS CHEMISTRY AND PHYSICS (2024)

No Data Available