Journal
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
Volume 21, Issue 4, Pages 413-418Publisher
SPRINGER
DOI: 10.1016/S1006-706X(14)60064-9
Keywords
Ca species; adsorption; alpha-Fe2O3 (001) surface; reduction differentiation index; CASTEP program
Categories
Funding
- National Natural Science Foundation of China [51174074]
- Open Fund Project of National Key Laboratory in University of Science and Technology Beijing of China [KF13-02]
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CaCl2 can be sprayed onto sinter surface, which can improve the low temperature reduction degradation index (RDI+3.15) of sinter. This has been recognized; however, there are various opinions on the inhibition mechanism of it. At the same time, the corrosion of Cl element on equipment is very serious. First-principle calculations based on density functional theory were performed to investigate the binding mechanisms of calcium species on a alpha-Fe2O3 (0 0 1) surface. This is crucial in demonstrating the role of the CaCl2 on improving the low temperature reduction degradation index. It has been determined that Cl could greatly increase the adsorption of the vacuum layer for the Ca/Fe2O3 system and the relaxation produced by adsorption made bond length decrease, bond energies increase and structure compact. Those are the main reasons that inhibiting the reduction disintegration of sinter.
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