4.5 Article

Study of Structure and Dielectric Properties of (Ba1-xCax)(Ti0.82Zr0.18)O3 Ceramics

Journal

JOURNAL OF INORGANIC MATERIALS
Volume 26, Issue 6, Pages 655-658

Publisher

SCIENCE PRESS
DOI: 10.3724/SP.J.1077.2011.00655

Keywords

BCZT ceramics; solid solubility; tetragonality of c/a; dielectric properties

Funding

  1. National Natural Science foundation of China [11074203]
  2. Talents foundation of Xihua university [R0620109]
  3. Key Disciplinary of Materials Science [XZD0814-09-1]
  4. Xihua University [YCJJ200924]

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(Ba1-xCax)(Ti0.82Zr0.18)O-3(BCZT, 0 <= x <= 0.26) ceramics was prepared by a solid phase reaction. The effect of Ca2+ doping on the microstructure and dielectric properties of the ceramics was studied. Results showed that the solid solubility lay around x=0.16 for BCZT ceramics while the second phase was observed. The value of c/a changed as the U-type curve with the variation of the Ca2+, and the minimum of the c/a was 1.00276 at x=0.06. It was found that Ca2+ ion substitution can be almost incorporated into the A site by the calculation of the tolerance factor and lattice constant. With increasing Ca2+ ion content, the grain size was decreased. The Curie temperature was shifted to low temperature, and the epsilon(r)-T peak was decreased and broaden. The relaxor characteristics were obtained while Ca2+ ion content was further increased.

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