Journal
JOURNAL OF INORGANIC MATERIALS
Volume 25, Issue 1, Pages 23-26Publisher
SCIENCE PRESS
DOI: 10.3724/SP.J.1077.2010.00023
Keywords
thermoelectric materials; Ba-filled; skutterudite; high pressure synthesis
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Polycrystalline skutterudite compounds BaxCo4Sb12(0.2 <= x <= 0.8) were successfully synthesized by solid state reaction under high pressure (2-5GPa). The crystallographic figures and microstructure were characterized by X-ray diffraction and electron probe microanalysis separately. Seebeck coefficient and electrical resistivity were measured at room temperature. The results show that high-pressure synthesis method can improve the Ba-filled content effectively. The samples have few micro-pores with fine-grained structure, their grain diameter sizes are in the micro-nanometer range. The maximum power factor value of the sample Ba0.8Co4Sb12 obtained at 4.25GPa is 13.19 mu W/(cm . K-2).
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