Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 24, Issue 3, Pages 644-651Publisher
SPRINGER
DOI: 10.1007/s10904-014-0028-x
Keywords
MOFs; Polymer; Luminescent property; Thermogravimetric analysis; Kinetics; 4,4 '-Dipyridyl
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One-dimensional structure of Zinc(II) metal organic framework ([Zn-2(C10H8N2)(3)(NO3)(4)](a)) has been synthesized at room temperature and structurally characterized by elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. The five-coordinated Zn(II) complex exhibits trigonal bipyramidal coordination geometry. The Zn(II) ion is stabilized by three-connected nodes to form 1D ladder structure. The 1D chain is further connected to each other via hydrogen bonding to form 2D structure. Disordered CH2Cl2 solvent molecules were trapped in the pores. The luminescent and thermal properties have been also investigated. In addition, the activation thermodynamic parameters, Delta E-*, Delta H-*, Delta S-* and Delta G(*) are calculated from the DTA curves using Coats-Redfern method.
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