Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 24, Issue 2, Pages 457-467Publisher
SPRINGER
DOI: 10.1007/s10904-013-0017-5
Keywords
Polymer anchored; Iron(III) complex; Oxidative bromination, H2O2
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Funding
- Department of Science and Technology (DST)
- Council of Scientific and Industrial Research (CSIR), New Delhi, India
- CSIR, New Delhi
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A polymer-anchored iron(III) catalyst was synthesized and characterized. Its catalytic activity was evaluated for the oxidation of various alkenes, sulfides, aromatic alcohols and ethylbenzene with 30 % H2O2 as the oxidizing agent. The catalyst was also effective for the oxidative bromination reaction with 80-100 % selectivity of monobrominated products with H2O2/KBr at room temperature. The above reactions require a minimum amount of H2O2 and short reaction time. Most importantly, all the above reactions occur in aqueous medium. The catalyst can be facilely recovered and reused six-atimes without significant decrease in its activity and selectivity.
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