4.7 Article

A pilot-scale TiO2 photocatalytic system for removing gas-phase elemental mercury at Hg-emitting facilities

Journal

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 19, Issue 1, Pages 144-149

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2012.07.016

Keywords

Mercury; Coal-fired power plant; Waste incinerator; Photocatalyst; Fluorescent light

Funding

  1. National Research Foundation of Korea (NRF)
  2. Korea Government (MEST) [2009-0079977]
  3. National Research Foundation of Korea [2009-0079977] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A pilot-scale TiO2 photocatalytic system using common household fluorescent lamps was tested at a real combustion facility for its ability to control Hg-0 emissions. An Hg-0 removal efficiency of greater than 90% was achieved under optimum conditions. The photocatalytic reaction units connected in series were more efficient than those connected in parallel. Acid components of the flue gas, such as NO and H2O, exhibited significant negative effects on the Hg-0 removal efficiency. There was no difference in Hg-0 removal efficiency between the systems employing mono-wavelength and tri-wavelength fluorescent lamps, and the efficiency was enhanced by increasing the amount of irradiation. (C) 2012 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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